{"id":"W2331803880","doi":"10.1021/ic402702z","title":"Physicochemical Analysis of Ruthenium(II) Sensitizers of 1,2,3-Triazole-Derived Mesoionic Carbene and Cyclometalating Ligands","year":2014,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":89,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia; University of Calgary","funders":"","keywords":"Ruthenium; Chemistry; Mesoionic; Carbene; Transmetalation; Photoredox catalysis; Photochemistry; Pyridine; Ligand (biochemistry); Carbanion; Dye-sensitized solar cell; Combinatorial chemistry; Catalysis; Stereochemistry; Medicinal chemistry; Organic chemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002667959,0.00056135,0.001444229,0.0000983537,0.0001416448,0.00002703767,0.0005551163,0.0005487603,0.001692217],"category_scores_gemma":[0.0004742626,0.0006019368,0.0005397621,0.0009899305,0.0004907547,0.00009422652,0.0006303248,0.0005181026,0.000002367435],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001493139,"about_ca_system_score_gemma":0.0001151016,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007306838,"about_ca_topic_score_gemma":0.000002953294,"domain_scores_codex":[0.9967806,0.00001814748,0.001208899,0.0008535695,0.0005970714,0.0005416747],"domain_scores_gemma":[0.9970371,0.0003879251,0.0008369447,0.001254898,0.0002115678,0.0002716132],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004971253,0.0001444865,0.002935667,0.0006463821,0.001551216,0.000002573802,0.0006657628,0.0000282226,0.9933385,0.00002080432,0.00004075642,0.0005758752],"study_design_scores_gemma":[0.001222728,0.00001827731,0.0003894021,0.0001280964,0.002009773,0.0000469293,0.0005824883,0.001536731,0.9933475,0.0000979505,0.00008340905,0.0005367634],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910676,0.0004369569,0.00007207647,0.00005698239,0.00006129034,0.00005079341,0.0001035142,0.0001283434,0.0080224],"genre_scores_gemma":[0.9987168,0.0001173972,0.000184473,0.00002890111,0.000305622,0.000005833917,0.0001766351,0.00008578382,0.0003785982],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007649112,"threshold_uncertainty_score":0.9996432,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00472141114922484,"score_gpt":0.2071344431198835,"score_spread":0.2024130319706586,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}