{"id":"W2331805834","doi":"10.1002/0471264229.os092.08","title":"Preparation of <i>N</i> ‐(Boc)‐Allylglycine Methyl Ester Using a Zinc‐Mediated, Palladium‐Catalyzed Cross‐Coupling Reaction","year":2016,"lang":"en","type":"other","venue":"Organic Syntheses","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Palladium; Catalysis; Zinc; Phosphine; Bromide; Context (archaeology); Negishi coupling; Yield (engineering); Coupling reaction; Organic chemistry; Medicinal chemistry; Combinatorial chemistry; Metallurgy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002265241,0.0003602466,0.0005428612,0.0001265112,0.0000482932,0.00003423645,0.0002623889,0.0005769235,0.001853999],"category_scores_gemma":[0.0006928159,0.0002824461,0.0002609913,0.0001308609,0.0001277546,0.000007212576,0.0001255367,0.00008778906,0.00006863358],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004623891,"about_ca_system_score_gemma":0.0001027883,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001514777,"about_ca_topic_score_gemma":0.0001273027,"domain_scores_codex":[0.9983546,0.00004572574,0.0004538489,0.0006086772,0.0002594376,0.0002777615],"domain_scores_gemma":[0.9984884,0.0001167351,0.0005716734,0.0006392719,0.00009130038,0.00009263372],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007975817,0.00006343137,0.0002751067,0.00007757479,0.0003740442,0.000001422374,0.000008466026,0.00000274324,0.9954779,0.000002418245,0.003026157,0.0006109478],"study_design_scores_gemma":[0.000242066,0.00003019134,0.00001819688,0.0003792488,0.0002726387,0.000008942829,0.00001360738,0.00006273347,0.9212068,0.000006522122,0.07739648,0.000362509],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8675365,0.01097046,0.009006812,0.0002651,0.001095372,0.001211669,0.000733151,0.000300089,0.1088809],"genre_scores_gemma":[0.9126968,0.002159907,0.0008150197,0.00005167174,0.001446602,0.00002382864,0.0003436429,0.0005913514,0.08187117],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07437032,"threshold_uncertainty_score":0.9999627,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01412237374853003,"score_gpt":0.2967664558717284,"score_spread":0.2826440821231984,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}