{"id":"W2331809099","doi":"10.1021/ja512389y","title":"Chemoselective Hydrogenation of Carbonyl Compounds and Acceptorless Dehydrogenative Coupling of Alcohols","year":2015,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":151,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University","funders":"Government of Ontario; Natural Sciences and Engineering Research Council of Canada; Wilfrid Laurier University","keywords":"Chemistry; Formamides; Chemoselectivity; Catalysis; Organic chemistry; Coupling (piping); Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001415459,0.000412567,0.0002361777,0.0001959841,0.0002074951,0.0001473469,0.0003863692,0.0002140473,0.001773672],"category_scores_gemma":[0.0001561581,0.0001387357,0.0001698269,0.0001882632,0.0002531204,0.0004075455,0.0004089245,0.0004400837,0.0007247425],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003437746,"about_ca_system_score_gemma":0.0002565185,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007602887,"about_ca_topic_score_gemma":0.002051807,"domain_scores_codex":[0.9998412,0.00001290225,0.00001133496,0.00002673508,0.00004403534,0.00006387282],"domain_scores_gemma":[0.9999459,0.000005771508,0.0000110837,0.00001198786,0.00001133606,0.00001399625],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001431804,0.00004589397,0.0003573309,0.0001238981,0.00001102143,0.0001951691,0.00006377778,0.0001848134,0.9889993,0.001209104,0.0002569475,0.008409724],"study_design_scores_gemma":[0.000004926138,0.00005381639,0.0002669075,0.000001830105,0.000002813459,0.00009020141,0.00001363904,0.0001148017,0.9977269,0.00005283566,0.001668646,0.000002807236],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9618329,0.001260113,0.01544791,0.000210905,0.00008901201,0.00008721031,0.0005614021,0.000207597,0.02030303],"genre_scores_gemma":[0.9941589,0.0005792956,0.00187706,0.00002607484,0.000009202979,0.0000145359,0.0002272048,0.00002587903,0.003081782],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001773672,"threshold_uncertainty_score":0.005933583,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01783379335963647,"score_gpt":0.2681026726710577,"score_spread":0.2502688793114212,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}