{"id":"W2331847931","doi":"10.15278/isms.2015.tb04","title":"FAR-INFRARED SYNCHROTRON-BASED SPECTROSCOPY OF PROTON TUNNELLING IN MALONALDEHYDE","year":2015,"lang":"en","type":"article","venue":"","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"","keywords":"Quantum tunnelling; Excited state; Ground state; Spectroscopy; Infrared; Chemistry; Atomic physics; Materials science; Physics; Optics; Optoelectronics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002120747,0.0002361212,0.0001478757,0.0004814877,0.000257524,0.0001350289,0.0002995932,0.000276508,0.0009059483],"category_scores_gemma":[0.0001881137,0.0001078027,0.00009808593,0.0004389572,0.000279302,0.0002447382,0.0002025257,0.0003609419,0.0001433704],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001739331,"about_ca_system_score_gemma":0.0001200502,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001109434,"about_ca_topic_score_gemma":0.001708857,"domain_scores_codex":[0.9999118,0.00001527185,0.000002600416,0.00001690362,0.00002621625,0.00002722845],"domain_scores_gemma":[0.9998635,0.00003287974,0.00002931622,0.00001280335,0.00004017782,0.00002132323],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000747673,0.00002037254,0.001999342,0.0000324168,0.000006676207,0.00003839325,0.00005080446,0.0001226482,0.9961492,0.0001045501,0.00006263059,0.001338223],"study_design_scores_gemma":[0.0000249032,0.0003558651,0.05965809,0.00001579727,0.00002681392,0.0003563002,0.0002790613,0.003421678,0.9341913,0.0002313515,0.00141269,0.00002614436],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949244,0.000498376,0.003464432,0.0000416157,0.000007465192,0.000006538086,0.0002150884,0.00005202523,0.000789937],"genre_scores_gemma":[0.9956051,0.0002794374,0.003259866,0.00003188493,0.00000426616,0.000007249595,0.0002263493,0.000007214923,0.0005786004],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001109434,"threshold_uncertainty_score":0.003030717,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01328240516285465,"score_gpt":0.2563068356870705,"score_spread":0.2430244305242158,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}