{"id":"W2331943839","doi":"10.1021/jp107285r","title":"In Situ High-Pressure Study of Sodium Amide by Raman and Infrared Spectroscopies","year":2010,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Hydrogen Storage and Materials","field":"Materials Science","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Raman spectroscopy; Orthorhombic crystal system; Infrared; Chemistry; Infrared spectroscopy; Ambient pressure; Diamond anvil cell; Amide; Analytical Chemistry (journal); High pressure; Sodium; Crystal structure; Crystallography; Thermodynamics; Organic chemistry; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001963924,0.0003254805,0.0001793367,0.0001441242,0.0001767237,0.0002694188,0.0003500462,0.0002728943,0.001192803],"category_scores_gemma":[0.0001675639,0.0001974173,0.0001457915,0.0001487444,0.0003640943,0.0005047601,0.0003264215,0.0004001298,0.0001937884],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001229447,"about_ca_system_score_gemma":0.00009005598,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003469164,"about_ca_topic_score_gemma":0.0004938987,"domain_scores_codex":[0.9998484,0.00001680457,0.000005314827,0.00002724059,0.00008044716,0.00002174993],"domain_scores_gemma":[0.9999014,0.00003035934,0.00002773402,0.000007878487,0.00002345311,0.000009048628],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000254905,0.000008236737,0.00015089,0.00003524822,0.000004015896,0.00004520659,0.00004167535,0.00005413669,0.9985812,0.00007341142,0.0000247866,0.0009557622],"study_design_scores_gemma":[0.00000526145,0.00008642449,0.001431577,0.000002987883,0.000005358545,0.0001544516,0.00006703362,0.0008859829,0.9961432,0.00004505319,0.001167471,0.00000539702],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9923689,0.000726136,0.003687099,0.000069673,0.0000235317,0.00001868212,0.0001354856,0.00004687538,0.002923525],"genre_scores_gemma":[0.9927894,0.0006335145,0.004373947,0.0000277639,0.00003160611,0.00002024698,0.0001416466,0.00002215816,0.001959614],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001192803,"threshold_uncertainty_score":0.003990352,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004457760901917899,"score_gpt":0.2400259289177621,"score_spread":0.2355681680158442,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}