{"id":"W2332071391","doi":"10.1021/om500938u","title":"Ortho Derivatization of Phenols through C–H Nickelation: Synthesis, Characterization, and Reactivities of Ortho-Nickelated Phosphinite Complexes","year":2014,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Chemistry; Phosphinite; Moiety; Toluene; Ligand (biochemistry); Aryl; Adduct; Medicinal chemistry; Bromide; Derivatization; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002737077,0.0003141842,0.0007853481,0.000139198,0.0001302907,0.00004495928,0.0002683038,0.0001720145,0.009605053],"category_scores_gemma":[0.0004544618,0.0003114134,0.0001463891,0.0006786471,0.0002892323,0.0004350238,0.0001322458,0.0001166438,0.00001042436],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003050884,"about_ca_system_score_gemma":0.00005128465,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003815968,"about_ca_topic_score_gemma":0.00001383205,"domain_scores_codex":[0.997999,0.00006904836,0.0008912343,0.0004192978,0.0003789121,0.0002425066],"domain_scores_gemma":[0.9977176,0.0004761739,0.0008581698,0.0006502073,0.0002225444,0.000075327],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003136313,0.000214733,0.01222846,0.0004317159,0.000333723,4.04805e-7,0.0007254804,0.00001182449,0.9499164,0.0153027,0.000003495827,0.02079967],"study_design_scores_gemma":[0.0005085386,0.00004549876,0.05478409,0.0001874662,0.0005209395,0.0000110017,0.0004625658,0.0005498503,0.8958821,0.0010478,0.04541381,0.0005863341],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.979868,0.0002546365,0.005935611,0.0001597151,0.00002683853,0.0001092845,0.0001467192,0.00008158194,0.01341763],"genre_scores_gemma":[0.9967979,0.0005130279,0.001183408,0.00002828144,0.00004804489,0.00001785763,0.0004750742,0.00006592507,0.0008704851],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05403432,"threshold_uncertainty_score":0.9999338,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01163840939072196,"score_gpt":0.2053384334988596,"score_spread":0.1937000241081376,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}