{"id":"W2332097456","doi":"10.1021/ol400542b","title":"Synthesis and Reactivity of Unsymmetrical Azomethine Imines Formed Using Alkene Aminocarbonylation","year":2013,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Alkene; Reactivity (psychology); Intermolecular force; Ketone; Combinatorial chemistry; Molecule; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001075027,0.0001251161,0.0002246198,0.0001049349,0.00005579032,0.00002818684,0.00008615385,0.00008707777,0.0006656217],"category_scores_gemma":[0.0005436031,0.0001101319,0.00005643255,0.0002383107,0.00007298788,0.0002140096,0.00003872099,0.0000959286,0.00001087275],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008695599,"about_ca_system_score_gemma":0.00001930624,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005752145,"about_ca_topic_score_gemma":0.000004429423,"domain_scores_codex":[0.9992062,0.00001462821,0.0002285468,0.0002040679,0.0001804476,0.0001660515],"domain_scores_gemma":[0.998947,0.0005435477,0.000150108,0.0002590181,0.00003746996,0.00006282231],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000003728128,0.00003877314,0.003982461,0.00004007799,0.00004159926,8.782416e-7,0.00005296052,9.556752e-7,0.9824183,0.00001615215,0.0001182709,0.01328581],"study_design_scores_gemma":[0.000133753,0.000003656853,0.01923618,0.00002908043,0.0000897881,0.00002308363,0.000105028,0.0006520401,0.9794757,0.00005090855,0.00007443869,0.0001263344],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9975843,0.00005448899,0.0004797005,0.001163664,0.00003864005,0.00005236368,0.000004528308,0.00003157804,0.0005906799],"genre_scores_gemma":[0.9991129,0.00001937669,0.0006263193,0.00009565803,0.00008208173,0.00001038222,0.000004110736,0.00002228728,0.00002690594],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01525372,"threshold_uncertainty_score":0.7288091,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01847395014119168,"score_gpt":0.226368694905012,"score_spread":0.2078947447638204,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}