{"id":"W2332125503","doi":"10.1021/om101025c","title":"Formation and Reactivity of a Transient Cationic Alkyl Phosphinidene Complex","year":2011,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Regina","funders":"","keywords":"Phosphinidene; Chemistry; Diphenylacetylene; Cationic polymerization; Reactivity (psychology); Cycloaddition; Phosphine; Medicinal chemistry; Stereochemistry; Crystallography; Catalysis; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002164735,0.0002960655,0.0002379568,0.000158059,0.0002653618,0.0005795816,0.0004490844,0.0005476045,0.002489061],"category_scores_gemma":[0.0004060715,0.0001961404,0.000136546,0.0001834463,0.0003016953,0.0003973737,0.0004395981,0.0005266455,0.0003947483],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006570491,"about_ca_system_score_gemma":0.0002965836,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009238304,"about_ca_topic_score_gemma":0.0008405577,"domain_scores_codex":[0.9997199,0.00002243481,0.00001418951,0.00006901451,0.00008204904,0.00009241251],"domain_scores_gemma":[0.9998228,0.00002882629,0.00004144053,0.00002344578,0.00003641237,0.0000470481],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001863364,0.00003701335,0.000216634,0.00006513141,0.00001249968,0.0001399008,0.00007436822,0.0004043178,0.9963288,0.0008239619,0.0001394128,0.001571602],"study_design_scores_gemma":[0.00002371532,0.0001777611,0.0005032396,0.000003186263,0.000006479372,0.0001295714,0.00001530351,0.0009475609,0.9967362,0.00006256676,0.001384383,0.000009938121],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942656,0.0003395224,0.001685661,0.0000627265,0.00001195986,0.00002420899,0.0001111922,0.00008060511,0.003418484],"genre_scores_gemma":[0.9970105,0.0001407465,0.0007355764,0.00002036943,0.00000307356,0.00001345472,0.0001744882,0.00001540342,0.00188644],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002489061,"threshold_uncertainty_score":0.008326709,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0551890999339876,"score_gpt":0.2196102505937202,"score_spread":0.1644211506597326,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}