{"id":"W2332255974","doi":"10.1021/jo102083g","title":"Phthalocyanine-Peptide Conjugates via Palladium-Catalyzed Cross-Coupling Reactions","year":2011,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Palladium; Catalysis; Phthalocyanine; Conjugate; Peptide; Chemistry; Coupling reaction; Coupling (piping); Combinatorial chemistry; Photochemistry; Polymer chemistry; Organic chemistry; Materials science; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004240364,0.0001637858,0.0002193444,0.00001396652,0.0001163509,0.00002455277,0.0004579172,0.0001347094,0.001427295],"category_scores_gemma":[0.0002413594,0.0001135095,0.0002288194,0.0001171622,0.0001436889,0.000007980208,0.00009671994,0.0002289032,0.0000156782],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002815754,"about_ca_system_score_gemma":0.0000689977,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001837053,"about_ca_topic_score_gemma":0.000003146536,"domain_scores_codex":[0.9989895,0.00001458468,0.0004743475,0.0001466192,0.0001702434,0.0002046938],"domain_scores_gemma":[0.9988521,0.00004008293,0.0004184352,0.0003646835,0.0002002986,0.0001243776],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009899477,0.000071874,0.001687434,0.00001777968,0.0002192648,0.000005985673,0.00004354261,0.00001074984,0.9975629,5.387625e-7,0.0001933709,0.00008755024],"study_design_scores_gemma":[0.0003260142,0.0000258299,0.000580594,0.00002457077,0.0001630967,0.0004375954,0.0001111776,0.00002762586,0.9969233,0.00007587553,0.001161598,0.0001427175],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969032,0.0006303634,0.0006654265,0.00008667662,0.00004958445,0.00002691089,0.000004169855,0.000006964849,0.001626705],"genre_scores_gemma":[0.9981431,0.0003697292,0.0002111627,0.00004124773,0.0004657978,8.573181e-7,0.0000116275,0.00002633093,0.0007301383],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001411617,"threshold_uncertainty_score":0.9994856,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01365988208404375,"score_gpt":0.2377294600215619,"score_spread":0.2240695779375182,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}