{"id":"W2332502537","doi":"10.1021/jp403586u","title":"Photoexcitation and Charge-Transfer-to-Solvent Relaxation Dynamics of the I<sup>–</sup>(CH<sub>3</sub>CN) Complex","year":2013,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Concordia University","funders":"Concordia University","keywords":"Photoexcitation; Charge (physics); Relaxation (psychology); Chemical physics; Solvent; Dynamics (music); Atomic physics; Chemistry; Physics; Physical chemistry; Computational chemistry; Excited state; Quantum mechanics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000090255,0.0001620647,0.0001074176,0.00007385237,0.0002371238,0.0001753895,0.0003670648,0.0002167992,0.001214755],"category_scores_gemma":[0.0002249065,0.00009736986,0.0001353968,0.0001148974,0.0002956641,0.0002262747,0.0001729532,0.0004134176,0.00009718174],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001102485,"about_ca_system_score_gemma":0.00038591,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.005437749,"about_ca_topic_score_gemma":0.004164474,"domain_scores_codex":[0.9999658,0.000002736136,9.363887e-7,0.00000785515,0.00001298843,0.000009644398],"domain_scores_gemma":[0.9999506,0.00002161163,0.0000118321,0.000003768264,0.000006649855,0.000005502954],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005628434,0.0001053292,0.004550572,0.0002252603,0.00004202567,0.000277443,0.0004848419,0.06600399,0.9084726,0.009216144,0.0006803466,0.009378586],"study_design_scores_gemma":[0.00006893329,0.0002911531,0.012489,0.00002060522,0.00002887613,0.0001763161,0.0002663024,0.3901962,0.5933594,0.001618547,0.001432188,0.00005257714],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976028,0.00008970964,0.00117197,0.0000445206,0.000003659806,0.000004007296,0.00004879285,0.00001774131,0.00101675],"genre_scores_gemma":[0.9989753,0.00004994587,0.0006435325,0.00001115283,5.367109e-7,0.000004809915,0.00005213801,0.000009217056,0.0002532765],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005437749,"threshold_uncertainty_score":0.01081222,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008001903064096873,"score_gpt":0.2251271198608872,"score_spread":0.2171252167967903,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}