{"id":"W2332556729","doi":"10.1021/cs400846j","title":"Surface Diastereomeric Complexes Formed by Methyl Benzoylformate and (<i>R</i>)-1-(1-Naphthyl)ethylamine on Pt(111)","year":2014,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Surface Chemistry and Catalysis","field":"Engineering","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval; Centre in Green Chemistry and Catalysis","funders":"","keywords":"Ethylamine; Chemistry; Steric effects; Diastereomer; Intermolecular force; Selectivity; Substrate (aquarium); Stereochemistry; Phenyl group; Medicinal chemistry; Molecule; Crystallography; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002066184,0.0004285909,0.0003903623,0.0001224403,0.0001779605,0.0004468696,0.0005653296,0.0004365661,0.001441724],"category_scores_gemma":[0.0003533825,0.0003380811,0.0002136373,0.0001771592,0.0002628837,0.0002655002,0.0002404759,0.0004072335,0.0002953173],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004967878,"about_ca_system_score_gemma":0.0001538121,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001484591,"about_ca_topic_score_gemma":0.001777704,"domain_scores_codex":[0.9997104,0.00004037138,0.00001241755,0.00007414818,0.00007165159,0.00009107561],"domain_scores_gemma":[0.9998602,0.00003436216,0.00005022714,0.00001576568,0.00001511975,0.0000243535],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001224953,0.00001198419,0.0002043632,0.00003967058,0.000009801342,0.00004634675,0.00004791066,0.000153215,0.9984146,0.0001195764,0.00004260181,0.0007873539],"study_design_scores_gemma":[0.00001425845,0.0001613226,0.0009030505,0.000003189063,0.000007948026,0.00006739477,0.00001759725,0.0008310691,0.9975152,0.00001606997,0.000458435,0.000004456525],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972089,0.0002554725,0.001304395,0.00002849434,0.000008181232,0.0000117386,0.00007440169,0.00004324159,0.001065085],"genre_scores_gemma":[0.9969106,0.0002417578,0.001583045,0.00002479465,0.000004286193,0.00001810253,0.000143254,0.00002885018,0.001045296],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001484591,"threshold_uncertainty_score":0.004823029,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006192496829375244,"score_gpt":0.1954748798008535,"score_spread":0.1892823829714783,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}