{"id":"W2332783741","doi":"10.1021/jp1081142","title":"Elucidating the Time Scale and Geometry of Phosphate and Phosphonate Rotation in Solid Acid Electrolytes Using Multinuclear NMR","year":2011,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Solid-state spectroscopy and crystallography","field":"Materials Science","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Phosphonate; Electrolyte; Chemistry; Proton; Ion; Phosphate; Thermal stability; Solid-state nuclear magnetic resonance; Inorganic chemistry; Crystallography; Chemical physics; Physical chemistry; Nuclear magnetic resonance; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002554637,0.0002399205,0.0001706507,0.0001544553,0.0001597528,0.0004096479,0.0002125355,0.0002032505,0.0007040472],"category_scores_gemma":[0.0004454285,0.0001565769,0.00007240898,0.0001586255,0.0003368855,0.0003761526,0.0001671248,0.0002933907,0.0001203913],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002319514,"about_ca_system_score_gemma":0.0002177382,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009987353,"about_ca_topic_score_gemma":0.001583708,"domain_scores_codex":[0.9999157,0.00001429531,0.000006101996,0.00002277306,0.00002633139,0.00001475966],"domain_scores_gemma":[0.9998888,0.00003890079,0.00002894956,0.000007979211,0.00002230755,0.00001309793],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009810692,0.000004549849,0.0003304856,0.00002865407,0.00000233829,0.00003528428,0.00005594417,0.0003093619,0.9972102,0.0002077171,0.00001488375,0.001702484],"study_design_scores_gemma":[0.000009388671,0.0001487754,0.002001576,0.000004663002,0.000006817889,0.000076072,0.00005167918,0.003833971,0.9929157,0.00008985741,0.0008503701,0.0000110517],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966091,0.0003768311,0.002199037,0.0000236492,0.000007226298,0.000009171543,0.000116177,0.00002737772,0.0006314701],"genre_scores_gemma":[0.9946144,0.000512681,0.004042887,0.000008421926,0.000003896041,0.00001135608,0.0001770253,0.00001411653,0.0006151635],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009987353,"threshold_uncertainty_score":0.002355278,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008382915877456385,"score_gpt":0.2377065036445956,"score_spread":0.2293235877671393,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}