{"id":"W2332860973","doi":"10.1021/ja513258j","title":"Synthesis and Tunability of Highly Electron-Accepting, N-Benzylated “Phosphaviologens”","year":2015,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Conducting polymers and applications","field":"Materials Science","cited_by":147,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation; Alberta Innovates - Technology Futures","keywords":"Chemistry; Viologen; Electrochromism; Substituent; Electron acceptor; Trifluoromethanesulfonate; Bipyridine; Combinatorial chemistry; Photochemistry; Medicinal chemistry; Organic chemistry; Crystal structure; Catalysis; Physical chemistry; Electrode","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009656954,0.0001689595,0.0000755041,0.00006718143,0.00006120435,0.0002042427,0.0002100799,0.0001601416,0.0008549254],"category_scores_gemma":[0.0002131181,0.00007928133,0.00008592384,0.00008934056,0.0001383149,0.0002463009,0.0001155944,0.0003652275,0.0001796627],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001433916,"about_ca_system_score_gemma":0.00008981525,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000167749,"about_ca_topic_score_gemma":0.0002642651,"domain_scores_codex":[0.9999461,0.000008031109,0.00000438546,0.00001778998,0.00001233974,0.00001123838],"domain_scores_gemma":[0.9999062,0.00002273578,0.00003548748,0.00001303168,0.00001098877,0.00001156048],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002827608,0.00001279442,0.00004172956,0.00002780872,0.000001886938,0.00003120947,0.00001710497,0.0001132656,0.9974106,0.0001521925,0.00002302089,0.002140103],"study_design_scores_gemma":[0.000003529438,0.00006099424,0.0001935838,7.312819e-7,0.000002411656,0.00003905217,0.000003208475,0.0002282609,0.9987504,0.00001196372,0.0007043248,0.000001366345],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9906431,0.0003008408,0.006513654,0.00005608893,0.00001183766,0.00002310762,0.0001191167,0.0000645688,0.002267761],"genre_scores_gemma":[0.9949067,0.0002472121,0.003466832,0.00001891204,0.000003425415,0.00001252661,0.0001249138,0.00002442652,0.001195012],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008549254,"threshold_uncertainty_score":0.002860069,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01874425642847802,"score_gpt":0.2750250841187973,"score_spread":0.2562808276903193,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}