{"id":"W2333068283","doi":"10.1021/ic200007v","title":"A Study of the Kinetics of La<sup>3+</sup>-Promoted Methanolysis of<i>S-</i>Aryl Methylphosphonothioates: Possible Methodology for Decontamination of EA 2192, the Toxic Byproduct of VX Hydrolysis","year":2011,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Edgewood Chemical Biological Center; Office of Science; Defense Threat Reduction Agency","keywords":"Chemistry; Methoxide; Sodium methoxide; Hydrolysis; Catalysis; Aryl; Kinetics; Nucleophile; Medicinal chemistry; Methanol; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008027854,0.0002632156,0.0009038569,0.00004803397,0.00004690964,0.00000384635,0.0008892228,0.0003309467,0.0005468022],"category_scores_gemma":[0.001879194,0.0001770396,0.0004734556,0.0006703932,0.0004361408,0.00004278617,0.0002326185,0.0002607965,3.103215e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005480609,"about_ca_system_score_gemma":0.0001004273,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004450106,"about_ca_topic_score_gemma":0.00001817346,"domain_scores_codex":[0.9977012,0.00008902854,0.001212754,0.0004009264,0.0003697167,0.0002263996],"domain_scores_gemma":[0.9952813,0.001596333,0.001385204,0.00124395,0.000443068,0.00005014284],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009663713,0.001697881,0.001687084,0.0007409424,0.0008480968,2.951673e-7,0.005006154,0.00002847761,0.9885628,0.00001276389,0.00001650093,0.001302424],"study_design_scores_gemma":[0.000835611,0.00007912173,0.000912502,0.0000927578,0.001164785,0.000008009074,0.004837339,0.00009188683,0.991424,0.0003743455,0.00002578128,0.0001538613],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978646,0.0003872798,0.0001237793,0.00006045934,0.00003099977,0.0002623796,0.0001179545,0.00001551108,0.001137044],"genre_scores_gemma":[0.9984857,0.00003949309,0.001113016,0.00000440331,0.00003578056,0.00004180618,0.00001206357,0.00003784708,0.0002298677],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002861257,"threshold_uncertainty_score":0.7219467,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04409207662781672,"score_gpt":0.2645307532089823,"score_spread":0.2204386765811656,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}