{"id":"W2333100581","doi":"10.1021/ma4009753","title":"Kinetics of Self-Immolative Degradation in a Linear Polymeric System: Demonstrating the Effect of Chain Length","year":2013,"lang":"en","type":"article","venue":"Macromolecules","topic":"Dendrimers and Hyperbranched Polymers","field":"Materials Science","cited_by":70,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Depolymerization; Polymer; Monomer; Degradation (telecommunications); Kinetics; Chemistry; Linear polymer; Chain (unit); Polymer chemistry; Polymer degradation; Chain scission; Cleavage (geology); Branching (polymer chemistry); Chemical engineering; Materials science; Organic chemistry; Computer science; Composite material; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004700856,0.0003240427,0.000218642,0.0001801042,0.0001127114,0.0002248797,0.0002359585,0.0002402694,0.0008655694],"category_scores_gemma":[0.0008659773,0.0001407912,0.0001909531,0.0001572301,0.0002857099,0.000466968,0.0001352542,0.000621652,0.0003414319],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002747835,"about_ca_system_score_gemma":0.0002216667,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005955728,"about_ca_topic_score_gemma":0.0005286227,"domain_scores_codex":[0.9997845,0.0000360242,0.00001373092,0.00006113914,0.0000693367,0.00003525742],"domain_scores_gemma":[0.9992574,0.0003806074,0.0001787156,0.00005849932,0.00008390693,0.00004095284],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008358537,0.00005396312,0.0003746303,0.00006810598,0.000008466825,0.00004215364,0.0001304266,0.0008182622,0.9947484,0.0001325422,0.00002902944,0.003510393],"study_design_scores_gemma":[0.000002802955,0.0002742969,0.0006233394,0.000003933925,0.000005139184,0.00003947908,0.00001115922,0.004619278,0.9940169,0.00003884641,0.0003601723,0.000004687409],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9808089,0.001652998,0.01594616,0.00004819068,0.00001356789,0.0000501175,0.0001194463,0.0001008977,0.001259804],"genre_scores_gemma":[0.9914807,0.0008196941,0.00593953,0.00002700195,0.000004649389,0.00003021697,0.00008306422,0.00002463261,0.001590514],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008655694,"threshold_uncertainty_score":0.002895653,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005414521189305518,"score_gpt":0.2180631854107895,"score_spread":0.212648664221484,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}