{"id":"W2333204479","doi":"10.1021/jp0496598","title":"Atmospheric Chemistry of<i>n-</i>C<i><sub>x</sub></i>F<sub>2</sub><i><sub>x</sub></i><sub>+1</sub>CHO (<i>x</i>= 1, 3, 4):  Reaction with Cl Atoms, OH Radicals and IR Spectra of C<i><sub>x</sub></i>F<sub>2</sub><i><sub>x</sub></i><sub>+1</sub>C(O)O<sub>2</sub>NO<sub>2</sub>","year":2004,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":47,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Analytical Chemistry (journal); Chemistry; Molar ratio; Infrared spectroscopy; Diluent; Nuclear chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007047597,0.0002390209,0.0001012763,0.0001126281,0.000324464,0.0001713371,0.0001983871,0.0003643529,0.001455892],"category_scores_gemma":[0.00009740402,0.00008923056,0.0001034044,0.00008662446,0.00019842,0.0001457993,0.00013341,0.0002544539,0.000147034],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005172577,"about_ca_system_score_gemma":0.0002288667,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.01536161,"about_ca_topic_score_gemma":0.01408176,"domain_scores_codex":[0.9999547,0.000002857129,9.981965e-7,0.00001729869,0.00001378731,0.00001034749],"domain_scores_gemma":[0.9999734,0.000004511548,0.000005437929,0.000002561252,0.000009015479,0.000004957991],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001112791,0.00001157597,0.004925658,0.00004785256,0.000008324517,0.00007277963,0.00006443424,0.0001795797,0.9922926,0.0001678008,0.000157498,0.001960493],"study_design_scores_gemma":[0.00001835504,0.0001999137,0.09011884,0.000009557707,0.00002263385,0.0001796847,0.0001259706,0.001435821,0.9038574,0.000140556,0.003877199,0.00001409799],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9963679,0.0002192947,0.0004951869,0.00004145212,0.00001263639,0.000008726888,0.0002190004,0.00003171157,0.002604044],"genre_scores_gemma":[0.9971594,0.0001884907,0.0005814927,0.00002220918,0.000005616409,0.000007176301,0.0002841713,0.00001145522,0.001740187],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01536161,"threshold_uncertainty_score":0.0305444,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005288926098163172,"score_gpt":0.1886842424366796,"score_spread":0.1833953163385164,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}