{"id":"W2333387239","doi":"10.1021/ja3106863","title":"Cleavage of DNA by Proton-Coupled Electron Transfer to a Photoexcited, Hydrated Ru(II) 1,10-Phenanthroline-5,6-dione Complex","year":2013,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Phenanthroline; Cleavage (geology); Electron transfer; Proton; Proton-coupled electron transfer; Photochemistry; Electron; Crystallography","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000140277,0.0002882962,0.0002387331,0.00007475756,0.00008249881,0.0002484181,0.0003519293,0.0004089127,0.001131492],"category_scores_gemma":[0.0003360797,0.0001411125,0.0001234847,0.00009142187,0.0001835807,0.0002051166,0.0001667116,0.0003955288,0.0002650202],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003784425,"about_ca_system_score_gemma":0.0001384109,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003119201,"about_ca_topic_score_gemma":0.0004558349,"domain_scores_codex":[0.9998615,0.00002196772,0.000006120064,0.00004616339,0.00003520967,0.00002912344],"domain_scores_gemma":[0.9998493,0.00004302878,0.00004661478,0.00001433347,0.00001374974,0.00003304014],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008136637,0.00001404245,0.0000779558,0.00003886493,0.000006764684,0.00003682996,0.0000288233,0.0001814223,0.9984185,0.00008122666,0.00002977861,0.001004455],"study_design_scores_gemma":[0.00001688257,0.0002274223,0.0008311579,0.000003106601,0.000005861119,0.0001129264,0.0000110363,0.001261604,0.9966209,0.00003525836,0.000868439,0.000005557808],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9955418,0.0004799567,0.003058132,0.00004179167,0.00001690036,0.00002781558,0.0000595144,0.0000810379,0.000693108],"genre_scores_gemma":[0.9970578,0.0001441395,0.001524349,0.00002326994,0.000003387502,0.00001016476,0.0001044429,0.0000114828,0.00112086],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001131492,"threshold_uncertainty_score":0.003785253,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02043332018740956,"score_gpt":0.2620813181598308,"score_spread":0.2416479979724212,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}