{"id":"W2333479717","doi":"10.1021/om4007483","title":"Bridging Rhodium–Iron Borataaminocarbyne Complexes Formed by Intramolecular Isonitrile–Borane Coordination","year":2013,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Rhodium; Borane; Medicinal chemistry; Ligand (biochemistry); Intramolecular force; Aryl; Alkyl; Stereochemistry; Catalysis; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001601321,0.0004118432,0.0003172613,0.00009109719,0.0001254541,0.000321691,0.0005882764,0.0003626978,0.001550378],"category_scores_gemma":[0.0001806234,0.000277568,0.0001656112,0.0001165737,0.0001906759,0.0002135383,0.0003474067,0.0005067093,0.0004296014],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004459836,"about_ca_system_score_gemma":0.0002059055,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009236236,"about_ca_topic_score_gemma":0.001501633,"domain_scores_codex":[0.9998429,0.0000186506,0.00001078281,0.0000432767,0.00003194105,0.00005245057],"domain_scores_gemma":[0.9999193,0.000009370032,0.00001820174,0.00001368169,0.000009422669,0.00002998033],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001848304,0.00003797604,0.00008114375,0.00004746145,0.00001023544,0.00005702021,0.00004325422,0.0001960848,0.9976743,0.0003345969,0.00005285414,0.001280289],"study_design_scores_gemma":[0.00006681178,0.0002247461,0.0008042501,0.000006020387,0.00001337084,0.00007804461,0.00001295035,0.001218283,0.9958004,0.00003717845,0.001728849,0.000008977104],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.994684,0.000269014,0.001989783,0.00003179464,0.00001452647,0.00004885639,0.00005413472,0.00009317325,0.002814605],"genre_scores_gemma":[0.9956767,0.0001747367,0.001813841,0.00002147252,0.000004459428,0.00002613979,0.000164977,0.00002145852,0.002096115],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001550378,"threshold_uncertainty_score":0.005186498,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006715046294425313,"score_gpt":0.2108845572906003,"score_spread":0.204169510996175,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}