{"id":"W2333486090","doi":"10.1021/om101024x","title":"Synthesis, Structure, and Reactivity of Iridium NHC Pincer Complexes","year":2011,"lang":"en","type":"article","venue":"Organometallics","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":56,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University","funders":"","keywords":"Pincer movement; Iridium; Chemistry; Reactivity (psychology); Pyridine; Pincer ligand; Medicinal chemistry; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0000771964,0.0002786005,0.0004464682,0.00004025836,0.00007344277,0.00001872301,0.0003584801,0.0002207709,0.0139601],"category_scores_gemma":[0.0001639655,0.0002672304,0.00009140994,0.0001511727,0.0003143578,0.0001286125,0.0002712727,0.0002374204,0.00001098813],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006264281,"about_ca_system_score_gemma":0.00005336096,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009094398,"about_ca_topic_score_gemma":0.00001118166,"domain_scores_codex":[0.9986816,0.00001360834,0.0003759976,0.0004100584,0.0002318016,0.0002869143],"domain_scores_gemma":[0.9987957,0.0001167237,0.0002363014,0.0006559119,0.0000615806,0.0001337533],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002721539,0.00009912355,0.004420576,0.0002301193,0.000101946,0.000003999554,0.0002773078,4.968328e-8,0.9923278,0.0004343389,0.00009830876,0.001979207],"study_design_scores_gemma":[0.0002307217,0.00001110846,0.004261971,0.0000316417,0.0001075959,0.0000661055,0.0001644624,0.000004641764,0.9912429,0.0007986133,0.002794655,0.0002855498],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9720391,0.0003825396,0.00004194268,0.00002280024,0.00008998296,0.00004067952,0.000149028,0.00007701841,0.02715693],"genre_scores_gemma":[0.9983025,0.0002410417,0.0007249495,0.0000303157,0.0001302581,0.000003757021,0.00001871349,0.00005634523,0.0004921356],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02666479,"threshold_uncertainty_score":0.999978,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02108890596097506,"score_gpt":0.2171825003141415,"score_spread":0.1960935943531665,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}