{"id":"W2333486090","doi":"10.1021/om101024x","title":"Synthesis, Structure, and Reactivity of Iridium NHC Pincer Complexes","year":2011,"lang":"en","type":"article","venue":"Organometallics","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":56,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University","funders":"","keywords":"Pincer movement; Iridium; Chemistry; Reactivity (psychology); Pyridine; Pincer ligand; Medicinal chemistry; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001947641,0.0003470324,0.0003036999,0.0002513983,0.0003178377,0.0005042242,0.0006484471,0.0003401989,0.002081231],"category_scores_gemma":[0.0003463954,0.0002165057,0.0001446597,0.00027449,0.000253208,0.0002835901,0.0003648282,0.0004629673,0.0003330523],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005835688,"about_ca_system_score_gemma":0.0002020645,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006366568,"about_ca_topic_score_gemma":0.0006543127,"domain_scores_codex":[0.9998253,0.00002484313,0.00001403962,0.00004430431,0.00004490186,0.00004655129],"domain_scores_gemma":[0.9999187,0.00001135524,0.000021742,0.00001467771,0.00001411111,0.00001949279],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005081072,0.00008455059,0.0002277169,0.0002610762,0.0000283957,0.0002173586,0.0001102691,0.001519065,0.9861578,0.002926727,0.0005177617,0.007441207],"study_design_scores_gemma":[0.0000852395,0.0004179128,0.0006238476,0.00001266017,0.00002173861,0.0002339449,0.00002521959,0.0008698385,0.9896712,0.0001388034,0.007874552,0.00002502485],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9810069,0.001996472,0.003452149,0.000140974,0.0000424926,0.0001189182,0.0003299409,0.0001221503,0.0127899],"genre_scores_gemma":[0.9921268,0.0008005976,0.002500894,0.00008241853,0.00001169427,0.00005517889,0.0003835474,0.00002770132,0.00401115],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002081231,"threshold_uncertainty_score":0.006962478,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02108890596097506,"score_gpt":0.2171825003141415,"score_spread":0.1960935943531665,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}