{"id":"W2333581853","doi":"10.1021/om400861d","title":"Unusual Redox Chemistry of Ytterbium Carbazole–Bis(oxazoline) Compounds: Oxidative Coupling of Primary Phosphines by an Ytterbium Carbazole–Bis(oxazoline) Dialkyl","year":2013,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Chemistry; Metathesis; Oxazoline; Ligand (biochemistry); Phosphine; Oxidative addition; Medicinal chemistry; Alkyl; Trigonal bipyramidal molecular geometry; Stereochemistry; Salt metathesis reaction; Crystallography; Alkylation; Crystal structure; Catalysis; Polymerization; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001099127,0.0002242773,0.0001163644,0.00007010323,0.0001202762,0.0003461561,0.0003494481,0.0002585272,0.0007988936],"category_scores_gemma":[0.00009476116,0.0001302595,0.0001159649,0.00007302203,0.0002169882,0.0001934001,0.0002426774,0.000338446,0.0002044956],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004288144,"about_ca_system_score_gemma":0.0001171508,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005655988,"about_ca_topic_score_gemma":0.001117902,"domain_scores_codex":[0.9999241,0.00001105508,0.000004906178,0.00001661588,0.0000175727,0.00002590037],"domain_scores_gemma":[0.9999751,0.000003259064,0.00000704186,0.000002454767,0.00000443105,0.000007736198],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005317784,0.00001143892,0.0000811341,0.00004108842,0.000005135746,0.000105336,0.00005698042,0.0000772851,0.9977021,0.0004739836,0.00005919988,0.001333197],"study_design_scores_gemma":[0.00002000993,0.00008739144,0.0004420053,0.000002173859,0.00000566455,0.0001528576,0.00001833152,0.0003924363,0.9961666,0.00005437639,0.002654664,0.000003336442],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.991006,0.001146058,0.004151892,0.0001471929,0.00003024196,0.00002761383,0.00007510304,0.0001143829,0.003301521],"genre_scores_gemma":[0.9964251,0.0004420713,0.001475281,0.00003102392,0.000005471328,0.00001105286,0.0000593322,0.00001093309,0.001539747],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007988936,"threshold_uncertainty_score":0.003111243,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01030236608466617,"score_gpt":0.2084743595098342,"score_spread":0.198171993425168,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}