{"id":"W2333581853","doi":"10.1021/om400861d","title":"Unusual Redox Chemistry of Ytterbium Carbazole–Bis(oxazoline) Compounds: Oxidative Coupling of Primary Phosphines by an Ytterbium Carbazole–Bis(oxazoline) Dialkyl","year":2013,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Chemistry; Metathesis; Oxazoline; Ligand (biochemistry); Phosphine; Oxidative addition; Medicinal chemistry; Alkyl; Trigonal bipyramidal molecular geometry; Stereochemistry; Salt metathesis reaction; Crystallography; Alkylation; Crystal structure; Catalysis; Polymerization; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004905584,0.001210797,0.002355405,0.0002564301,0.0002370782,0.0001902822,0.001888399,0.0006035853,0.01557346],"category_scores_gemma":[0.0002052856,0.00120809,0.0006990844,0.001221521,0.0007681878,0.0007557555,0.0007168213,0.0007165077,0.00004890882],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000353833,"about_ca_system_score_gemma":0.0004367432,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001603232,"about_ca_topic_score_gemma":0.00008491008,"domain_scores_codex":[0.9937647,0.00004725284,0.002314657,0.001441721,0.001301562,0.001130132],"domain_scores_gemma":[0.9943901,0.0003592038,0.001583389,0.002258039,0.0008028018,0.0006064682],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007844557,0.0009069921,0.0024277,0.001145169,0.000809497,0.000007593848,0.0005667465,0.00007331776,0.9912787,0.0000635118,0.0009342523,0.001708052],"study_design_scores_gemma":[0.001388669,0.00009563057,0.001640246,0.000168837,0.0006891987,0.00002023566,0.001058745,0.001447411,0.9804099,0.0001040881,0.01161194,0.001365077],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9851072,0.001944659,0.0002358944,0.0003055271,0.0001951813,0.0003702063,0.001397038,0.0002287441,0.01021558],"genre_scores_gemma":[0.9905102,0.0004118673,0.0007150399,0.00018511,0.0006060993,0.00009879583,0.003577201,0.0002810525,0.003614693],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01552455,"threshold_uncertainty_score":0.9990369,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01030236608466617,"score_gpt":0.2084743595098342,"score_spread":0.198171993425168,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}