{"id":"W2333582106","doi":"10.1021/om201214z","title":"Bis(diethylphosphino)methane As a Bridging Ligand in Complexes of Ir<sub>2</sub>, Rh<sub>2</sub>, and IrRh: Geminal C–H Activation of α-Olefins","year":2012,"lang":"en","type":"article","venue":"Organometallics","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Triflic acid; Iridium; Trifluoromethanesulfonate; Hydride; Rhodium; Protonation; Medicinal chemistry; Geminal; Ligand (biochemistry); Methylene; Catalysis; Stereochemistry; Hydrogen; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008928665,0.0002458594,0.0001896192,0.00009020887,0.0001128996,0.0001660329,0.0003926376,0.0001756601,0.0009902267],"category_scores_gemma":[0.00009225233,0.0001305138,0.00007598406,0.00009033379,0.0001507345,0.0001231724,0.0003244124,0.0002356242,0.0003341754],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003105163,"about_ca_system_score_gemma":0.0001221975,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006475257,"about_ca_topic_score_gemma":0.000948516,"domain_scores_codex":[0.9999424,0.00001146152,0.000003225594,0.000009427184,0.00001244255,0.00002106352],"domain_scores_gemma":[0.9999691,0.00000341585,0.000009010911,0.000004114545,0.000003090151,0.0000111841],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002925598,0.00003162358,0.0002394361,0.000113422,0.00001052664,0.00008740833,0.00008924475,0.000514749,0.994451,0.0004839184,0.0001483256,0.003537667],"study_design_scores_gemma":[0.00004735564,0.000300319,0.0009422685,0.000007345452,0.00001476524,0.0001370462,0.00003864203,0.001507437,0.9936678,0.00006240384,0.003267928,0.000006607462],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9953132,0.0004453992,0.001361089,0.00004400492,0.00001085247,0.00001397906,0.00003755117,0.00009072579,0.002683314],"genre_scores_gemma":[0.9975055,0.0002116864,0.0007797627,0.0000204177,0.000002801997,0.00001194198,0.00007294592,0.00001595258,0.001378982],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009902267,"threshold_uncertainty_score":0.003312588,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02138841720331036,"score_gpt":0.2614012368125959,"score_spread":0.2400128196092855,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}