{"id":"W2333881672","doi":"10.1021/ic010186i","title":"Solid-State Coordination Chemistry:  Structural Influences of Copper−Phenanthroline Subunits on Oxovanadium Organophosphonate Phases. Hydrothermal Synthesis and Structural Characterization of the Two-Dimensional Materials [Cu(phen)(VO)(O<sub>3</sub>PCH<sub>2</sub>PO<sub>3</sub>)(H<sub>2</sub>O)], [{Cu(phen)}<sub>2</sub>(V<sub>2</sub>O<sub>5</sub>)(O<sub>3</sub>PCH<sub>2</sub>CH<sub>2</sub>PO<sub>3</sub>)], and [{Cu(phen)}<sub>2</sub>(V<sub>3</sub>O<sub>5</sub>)(O<sub>3</sub>PCH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>PO<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>O)] and of the Three-Dimensional Phase [{Cu(phen)}<sub>2</sub>(V<sub>3</sub>O<sub>5</sub>)(O<sub>3</sub>PCH<sub>2</sub>PO<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>O)]","year":2001,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Chemical Synthesis and Characterization","field":"Environmental Science","cited_by":89,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Crystallography; Antiferromagnetism; Square pyramidal molecular geometry; Octahedron; Monoclinic crystal system; Phenanthroline; Magnetic susceptibility; Crystal structure; Hydrothermal synthesis; Paramagnetism; Ligand (biochemistry); Hydrothermal circulation; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005571768,0.0001749874,0.00009631195,0.00007078634,0.0001283516,0.0003655851,0.0002524533,0.0001227043,0.001796062],"category_scores_gemma":[0.0001878653,0.0001457342,0.00004709301,0.0001156481,0.000217436,0.0001667237,0.0001687192,0.0001725617,0.0002216037],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002694622,"about_ca_system_score_gemma":0.0001606235,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001136697,"about_ca_topic_score_gemma":0.002019215,"domain_scores_codex":[0.9999471,0.000007611109,0.000003707936,0.00001643697,0.00001102371,0.00001422577],"domain_scores_gemma":[0.9999415,0.00001507412,0.00001573567,0.000005178297,0.000009372957,0.00001308122],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002296451,0.00001546856,0.000433111,0.00008651022,0.000008030436,0.00004718547,0.00006941493,0.000262815,0.9963688,0.0004198298,0.0001376521,0.001921565],"study_design_scores_gemma":[0.00001886274,0.00008404625,0.002215178,0.000004288238,0.000007361284,0.00003887203,0.00004571072,0.0007773286,0.9947692,0.00006438632,0.001970513,0.000004323853],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9970739,0.0002128998,0.000576408,0.00002196007,0.000006907189,0.000008218205,0.0001373797,0.00003878137,0.001923615],"genre_scores_gemma":[0.9988045,0.0001139095,0.000301356,0.000007016687,0.000001254765,0.000006533781,0.0001387957,0.00001680135,0.0006096881],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001796062,"threshold_uncertainty_score":0.006008446,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006896789168142263,"score_gpt":0.2143423365630039,"score_spread":0.2074455473948616,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}