{"id":"W2333881672","doi":"10.1021/ic010186i","title":"Solid-State Coordination Chemistry:  Structural Influences of Copper−Phenanthroline Subunits on Oxovanadium Organophosphonate Phases. Hydrothermal Synthesis and Structural Characterization of the Two-Dimensional Materials [Cu(phen)(VO)(O<sub>3</sub>PCH<sub>2</sub>PO<sub>3</sub>)(H<sub>2</sub>O)], [{Cu(phen)}<sub>2</sub>(V<sub>2</sub>O<sub>5</sub>)(O<sub>3</sub>PCH<sub>2</sub>CH<sub>2</sub>PO<sub>3</sub>)], and [{Cu(phen)}<sub>2</sub>(V<sub>3</sub>O<sub>5</sub>)(O<sub>3</sub>PCH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>PO<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>O)] and of the Three-Dimensional Phase [{Cu(phen)}<sub>2</sub>(V<sub>3</sub>O<sub>5</sub>)(O<sub>3</sub>PCH<sub>2</sub>PO<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>O)]","year":2001,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Chemical Synthesis and Characterization","field":"Environmental Science","cited_by":89,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Crystallography; Antiferromagnetism; Square pyramidal molecular geometry; Octahedron; Monoclinic crystal system; Phenanthroline; Magnetic susceptibility; Crystal structure; Hydrothermal synthesis; Paramagnetism; Ligand (biochemistry); Hydrothermal circulation; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"category_scores_codex":[0.02819407,0.05540175,0.0466504,0.01824407,0.0261277,0.01639963,0.03528507,0.03414648,0.000924504],"category_scores_gemma":[0.01648531,0.06071097,0.02452418,0.04530141,0.03624832,0.03076961,0.02811063,0.0414368,0.008888059],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.03142145,"about_ca_system_score_gemma":0.02145161,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001399267,"about_ca_topic_score_gemma":0.01090389,"domain_scores_codex":[0.8060665,0.01780194,0.04779649,0.04609294,0.03831004,0.0439321],"domain_scores_gemma":[0.8575452,0.01695511,0.04664557,0.03357565,0.01745521,0.02782322],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.02461603,0.01825395,0.00488165,0.01189032,0.01612278,0.006782759,0.005826506,0.007705089,0.7888278,0.0004461436,0.01689683,0.09775018],"study_design_scores_gemma":[0.05148508,0.006510841,0.01472802,0.0162931,0.01939078,0.01234124,0.003894446,0.009828472,0.8097503,0.004322834,0.001487504,0.04996741],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8719518,0.01090852,0.002081027,0.004651282,0.02008064,0.03839731,0.03863299,0.0125551,0.0007413258],"genre_scores_gemma":[0.8559661,0.05281681,0.0007428396,0.007915776,0.01652965,0.01380145,0.03456223,0.01757318,0.00009195074],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05147872,"threshold_uncertainty_score":0.9999888,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006896789168142263,"score_gpt":0.2143423365630039,"score_spread":0.2074455473948616,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}