{"id":"W2333998586","doi":"10.1021/je100835n","title":"Temperature-Dependent Vapor Pressure of Selected Cyclic and Linear Polydimethylsiloxane Oligomers","year":2010,"lang":"en","type":"article","venue":"Journal of Chemical & Engineering Data","topic":"Odor and Emission Control Technologies","field":"Chemical Engineering","cited_by":57,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Vaporization; Vapor pressure; Polydimethylsiloxane; Isothermal process; Analytical Chemistry (journal); Oligomer; Aerosol; Calibration; Gas chromatography; Water vapor; Thermodynamics; Chromatography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002766619,0.0002105718,0.0004784868,0.0001466149,0.00001410114,0.00001948924,0.0008468334,0.0003169565,0.0000435804],"category_scores_gemma":[0.002401855,0.0001707876,0.00006644406,0.0002504618,0.00005170031,0.0002265472,0.0003057489,0.001316215,0.000001225345],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001168004,"about_ca_system_score_gemma":0.00003589282,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005757992,"about_ca_topic_score_gemma":1.441892e-7,"domain_scores_codex":[0.9986244,0.000006273432,0.0005619758,0.0002160516,0.0003235047,0.0002678349],"domain_scores_gemma":[0.9986706,0.000199626,0.0001926839,0.0005886854,0.0001554904,0.0001928654],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004123161,0.00004265395,0.00009514859,0.0001070208,0.0001435084,0.00001214015,0.00001753462,0.0005685615,0.9973531,0.0000425849,0.0005143814,0.001062118],"study_design_scores_gemma":[0.0006771858,0.0000346976,0.0000930945,0.00008723156,0.0001146173,0.0001578992,0.000007029621,0.02247759,0.9729564,0.00001499958,0.003197272,0.0001820335],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9965064,0.001493503,0.0009904932,0.0003338676,0.0003466597,0.00006998478,0.0000940461,0.0001385078,0.00002651772],"genre_scores_gemma":[0.9873685,0.00006958812,0.01214444,0.0000107753,0.0003095664,0.000001113687,0.0000207635,0.00003419727,0.00004105943],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02439676,"threshold_uncertainty_score":0.6964515,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009779606942250687,"score_gpt":0.2427959367071513,"score_spread":0.2330163297649006,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}