{"id":"W2334255479","doi":"10.1021/ic000825+","title":"Insertion Reactions of (PPh<sub>3</sub>)<sub>2</sub>Pt(SR)<sub>2</sub>with CS<sub>2</sub>, where R = H, CMe<sub>3</sub>, CHMe<sub>2</sub>, 4-C<sub>6</sub>H<sub>4</sub>Me; Structure of (PPh<sub>3</sub>)Pt(SC<sub>6</sub>H<sub>4</sub>Me)(S<sub>2</sub>CS-4-C<sub>6</sub>H<sub>4</sub>Me)","year":2001,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Crystallography; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","metaepi_broad","sts","open_science","research_integrity","insufficient_payload"],"category_scores_codex":[0.01198267,0.03091464,0.0285636,0.01119638,0.01186866,0.007406714,0.02285663,0.02372828,0.001418015],"category_scores_gemma":[0.009217606,0.03543922,0.01858637,0.03172567,0.01327842,0.01329531,0.01307597,0.03010019,0.008167848],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.02071561,"about_ca_system_score_gemma":0.01547171,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007489763,"about_ca_topic_score_gemma":0.008551924,"domain_scores_codex":[0.8832624,0.006213191,0.03008654,0.02991117,0.02322969,0.02729703],"domain_scores_gemma":[0.9066091,0.008200164,0.02646267,0.02962092,0.01260233,0.01650484],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.008057356,0.01332578,0.004197117,0.01192631,0.0144913,0.004032509,0.004310642,0.001921251,0.8338645,0.0002705834,0.01966593,0.08393673],"study_design_scores_gemma":[0.02569647,0.002828431,0.007696874,0.009719177,0.01649753,0.008913577,0.006322233,0.001790688,0.8823813,0.00263472,0.004160445,0.03135856],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9324027,0.01244659,0.001846906,0.002803809,0.008461071,0.01393144,0.01500691,0.01028504,0.002815574],"genre_scores_gemma":[0.89819,0.04802098,0.0005154744,0.002822716,0.01435299,0.005523776,0.0195815,0.01076489,0.0002276604],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05257816,"threshold_uncertainty_score":0.9994949,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00798766130902272,"score_gpt":0.2011924972112554,"score_spread":0.1932048359022326,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}