{"id":"W2334255479","doi":"10.1021/ic000825+","title":"Insertion Reactions of (PPh<sub>3</sub>)<sub>2</sub>Pt(SR)<sub>2</sub>with CS<sub>2</sub>, where R = H, CMe<sub>3</sub>, CHMe<sub>2</sub>, 4-C<sub>6</sub>H<sub>4</sub>Me; Structure of (PPh<sub>3</sub>)Pt(SC<sub>6</sub>H<sub>4</sub>Me)(S<sub>2</sub>CS-4-C<sub>6</sub>H<sub>4</sub>Me)","year":2001,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Crystallography; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001150931,0.0004086446,0.0002616098,0.000124451,0.0002052974,0.0002965194,0.0004454914,0.0003793959,0.003901399],"category_scores_gemma":[0.000213688,0.0002486344,0.0002696619,0.0002071099,0.00022759,0.0004094781,0.0003887917,0.0004419165,0.0008677838],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000459777,"about_ca_system_score_gemma":0.0002412243,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001273091,"about_ca_topic_score_gemma":0.001969155,"domain_scores_codex":[0.9998665,0.00001631328,0.000007105875,0.00003804015,0.00003533747,0.0000367671],"domain_scores_gemma":[0.9999264,0.00001743897,0.00002208187,0.00001110132,0.000007123482,0.00001575443],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004114176,0.00002322234,0.000205751,0.00009502372,0.00002422676,0.0001522139,0.00009838046,0.0003745382,0.9950979,0.0006024531,0.0001788719,0.002736004],"study_design_scores_gemma":[0.00001378171,0.0001661936,0.0003522486,0.000001422165,0.00001064752,0.0001788745,0.00001852976,0.0005364071,0.9969692,0.00008419502,0.001662944,0.000005573999],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9761202,0.001032692,0.01079571,0.0001485283,0.00008542009,0.00009146758,0.0002958083,0.0004836388,0.01094652],"genre_scores_gemma":[0.9871589,0.0002562664,0.002953255,0.00004225592,0.000006509738,0.00002164851,0.0002111922,0.00006680112,0.009283151],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003901399,"threshold_uncertainty_score":0.01305145,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00798766130902272,"score_gpt":0.2011924972112554,"score_spread":0.1932048359022326,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}