{"id":"W2334276619","doi":"10.1021/ic026269w","title":"Structural Diversity of Lithium Sulfenamides: <sup>7</sup>Li NMR Studies in Solution and Crystal Structures of [Li<sub>2</sub>(η<sup>2</sup>-(CH<sub>3</sub>)<sub>3</sub>C−NS−C<sub>6</sub>H<sub>4</sub>CH<sub>3</sub>-4)<sub>2</sub>(THF)<sub>2</sub>] and [Li<sub>2</sub>(η<sup>1</sup>-4-CH<sub>3</sub>C<sub>6</sub>H<sub>4</sub>−NS−C<sub>6</sub>H<sub>4</sub>CH<sub>3</sub>-4)<sub>2</sub>(THF)<sub>4</sub>]","year":2003,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Coordination Chemistry and Organometallics","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Sulfenamide; Crystal structure; Crystallography; Lithium (medication); Nuclear magnetic resonance spectroscopy; NMR spectra database; Toluene; Electron paramagnetic resonance; Stereochemistry; Medicinal chemistry; Spectral line; Organic chemistry; Nuclear magnetic resonance","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001156569,0.000190067,0.000167145,0.00009756718,0.0001491537,0.0002900909,0.0003950291,0.0002246602,0.001361213],"category_scores_gemma":[0.000231009,0.0001304807,0.00008560292,0.000152218,0.0003279618,0.0003517542,0.0001820987,0.0003444817,0.0002544942],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003644677,"about_ca_system_score_gemma":0.0002978503,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001934686,"about_ca_topic_score_gemma":0.002356424,"domain_scores_codex":[0.9999425,0.000007352675,0.000004561977,0.00001230771,0.00002213565,0.00001110108],"domain_scores_gemma":[0.9999053,0.00001198458,0.00003025463,0.000007452092,0.00002578607,0.00001917909],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002364985,0.00001433638,0.0003225426,0.00009189307,0.00001063097,0.00005819394,0.0001330594,0.0002660335,0.9960309,0.0005166696,0.0001103879,0.002208765],"study_design_scores_gemma":[0.00004133471,0.0002811406,0.002041269,0.000007477511,0.00002042091,0.0001930755,0.0001559417,0.001000538,0.9883112,0.0001404775,0.007788699,0.00001837976],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9952505,0.0006846831,0.001074809,0.00008490692,0.000008261492,0.00001128177,0.0002141219,0.00005669402,0.002614603],"genre_scores_gemma":[0.9947442,0.000515801,0.001761392,0.00004760755,0.000005232196,0.0000212835,0.0006543152,0.00002204066,0.002228134],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001934686,"threshold_uncertainty_score":0.004553735,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01627075860069048,"score_gpt":0.228664275461389,"score_spread":0.2123935168606985,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}