{"id":"W2334332969","doi":"10.1021/ja403955k","title":"Stereodirection of an α-Ketoester at Sub-molecular Sites on Chirally Modified Pt(111): Heterogeneous Asymmetric Catalysis","year":2013,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Surface Chemistry and Catalysis","field":"Engineering","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Chemistry; Chemisorption; Ethylamine; Diastereomer; Catalysis; Scanning tunneling microscope; Conformational isomerism; Substrate (aquarium); Amine gas treating; Density functional theory; Covalent bond; Stereochemistry; Computational chemistry; Molecule; Physical chemistry; Organic chemistry; Nanotechnology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000830124,0.0002022441,0.0002047912,0.0001003522,0.0001247117,0.0004007102,0.0003523511,0.0002460097,0.0007954953],"category_scores_gemma":[0.0001514264,0.0002012247,0.000150793,0.00008528955,0.0002498368,0.0002143248,0.0001692065,0.0003861545,0.0002404028],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003404121,"about_ca_system_score_gemma":0.0001110305,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006926004,"about_ca_topic_score_gemma":0.0007413568,"domain_scores_codex":[0.9998941,0.000009737751,0.000004754191,0.00002425584,0.00004321931,0.00002384224],"domain_scores_gemma":[0.9999391,0.0000134694,0.00001749652,0.000009228253,0.000009989785,0.00001063824],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004364635,0.000008213772,0.0001748268,0.00001511472,0.000003200037,0.00005928711,0.00001934792,0.0002088997,0.9984882,0.0001705614,0.00002145949,0.0007871236],"study_design_scores_gemma":[0.000006410754,0.00003689359,0.0007677378,0.000001087981,0.000003730583,0.00006977864,0.00001769019,0.002033789,0.996743,0.0000358631,0.0002812972,0.00000265847],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9974554,0.0001049455,0.001463692,0.00001941145,0.000007488723,0.000004627125,0.00002646984,0.00002629557,0.0008917249],"genre_scores_gemma":[0.9988996,0.00006180613,0.0006145068,0.000006931944,0.000001588981,0.000002288312,0.00002528558,0.000006260071,0.0003817876],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007954953,"threshold_uncertainty_score":0.002661169,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006415311852278578,"score_gpt":0.2034132869188996,"score_spread":0.1969979750666211,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}