{"id":"W2334533945","doi":"10.1021/cg300798p","title":"A Diphosphine Ligand with Amide Functionality and Its Complexes with Gold(I) and Silver(I): Self-Assembly of Sheet Structures","year":2012,"lang":"en","type":"article","venue":"Crystal Growth & Design","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Hydrogen bond; Chemistry; Ligand (biochemistry); Amide; Ribbon; Derivative (finance); Phosphine; Crystallography; Phosphine oxide; Polymer chemistry; Self-assembly; Stereochemistry; Molecule; Materials science; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001181274,0.0003316983,0.0001751589,0.0001416374,0.0001088354,0.000243231,0.0003281979,0.0002880981,0.0004905896],"category_scores_gemma":[0.0001541091,0.0002092724,0.0001364635,0.00008638968,0.0001899239,0.0001728604,0.0002175154,0.0002509596,0.0001754067],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002353933,"about_ca_system_score_gemma":0.00009517274,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002758542,"about_ca_topic_score_gemma":0.0004507657,"domain_scores_codex":[0.9999148,0.00001705683,0.000005668841,0.00001947478,0.00001934006,0.00002369264],"domain_scores_gemma":[0.9999241,0.00001555117,0.00002193598,0.000008779133,0.000006261897,0.00002330459],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008572588,0.00001907358,0.0001297204,0.00003917525,0.000006638305,0.00006060595,0.00004307667,0.0002231082,0.9975552,0.0001450734,0.00003437923,0.001658217],"study_design_scores_gemma":[0.0000190204,0.000237368,0.0007610266,0.000002529701,0.000007895637,0.0001225501,0.00001066677,0.0007951874,0.9971751,0.00002817746,0.000834315,0.000006237933],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9959299,0.0004585228,0.001760885,0.00003071943,0.000007592246,0.00001682888,0.00003625752,0.00006832845,0.001690987],"genre_scores_gemma":[0.9956137,0.0002233402,0.002763593,0.00003567685,0.000005801232,0.00002242746,0.00006587391,0.00001450502,0.001254944],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0004905896,"threshold_uncertainty_score":0.001707911,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01630949266428348,"score_gpt":0.2200005594509661,"score_spread":0.2036910667866826,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}