{"id":"W2334846522","doi":"10.1021/om990761e","title":"Ruthenium Cyclopentadienyl Aryldiazenido Complexes. Synthesis of [Cp‘Ru(PR<sub>3</sub>)<sub>2</sub>(N<sub>2</sub>C<sub>6</sub>H<sub>4</sub>OMe)][BF<sub>4</sub>]<sub>2</sub>and [Cp‘RuCl(PPh<sub>3</sub>)(N<sub>2</sub>C<sub>6</sub>H<sub>4</sub>OMe)][BF<sub>4</sub>] (Cp‘ = Cp, Cp*) and X-ray Crystal Structure of [CpRu(PPh<sub>3</sub>)<sub>2</sub>(N<sub>2</sub>C<sub>6</sub>H<sub>4</sub>OMe)][BF<sub>4</sub>]<sub>2</sub>, an Aryldiazenido Complex with a Large N−N−C(aryl) Angle and Near-Linear Ru−N−N−C(aryl) Skeleton","year":2000,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"","keywords":"Cyclopentadienyl complex; Ruthenium; Chemistry; Acetonitrile; Yield (engineering); Crystal structure; Medicinal chemistry; Nuclear magnetic resonance spectroscopy; Crystallography; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001473285,0.0003715109,0.0003510095,0.0001491525,0.0001677349,0.0002445527,0.0007922729,0.0002802898,0.002816663],"category_scores_gemma":[0.0001790894,0.0002690094,0.0001436274,0.0002480089,0.0001340783,0.0001921832,0.0002504705,0.0005992228,0.0006887817],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007043409,"about_ca_system_score_gemma":0.0002938473,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001512692,"about_ca_topic_score_gemma":0.002529648,"domain_scores_codex":[0.999863,0.00001667125,0.000009887697,0.00003231821,0.000040186,0.00003795768],"domain_scores_gemma":[0.9999431,0.000006751305,0.00001404256,0.00001135723,0.00001159294,0.00001309977],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000228846,0.00006116056,0.0001179725,0.0003429955,0.00003566723,0.00009456856,0.00005738615,0.0005360426,0.9904051,0.00223093,0.0008570786,0.00503233],"study_design_scores_gemma":[0.00009192558,0.0002694332,0.0009103871,0.00001108142,0.00002636451,0.0001890009,0.0000156871,0.001310191,0.9848718,0.0001023586,0.01218721,0.00001448987],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9333609,0.004923351,0.02865547,0.0003893231,0.0002412693,0.0004243471,0.001696938,0.000949648,0.02935879],"genre_scores_gemma":[0.9710675,0.002467875,0.0119899,0.0001453526,0.00001649275,0.0001787404,0.001209307,0.00008073697,0.01284411],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002816663,"threshold_uncertainty_score":0.009422719,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008557957750394743,"score_gpt":0.2033862601682346,"score_spread":0.1948283024178399,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}