{"id":"W2334846522","doi":"10.1021/om990761e","title":"Ruthenium Cyclopentadienyl Aryldiazenido Complexes. Synthesis of [Cp‘Ru(PR<sub>3</sub>)<sub>2</sub>(N<sub>2</sub>C<sub>6</sub>H<sub>4</sub>OMe)][BF<sub>4</sub>]<sub>2</sub>and [Cp‘RuCl(PPh<sub>3</sub>)(N<sub>2</sub>C<sub>6</sub>H<sub>4</sub>OMe)][BF<sub>4</sub>] (Cp‘ = Cp, Cp*) and X-ray Crystal Structure of [CpRu(PPh<sub>3</sub>)<sub>2</sub>(N<sub>2</sub>C<sub>6</sub>H<sub>4</sub>OMe)][BF<sub>4</sub>]<sub>2</sub>, an Aryldiazenido Complex with a Large N−N−C(aryl) Angle and Near-Linear Ru−N−N−C(aryl) Skeleton","year":2000,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"","keywords":"Cyclopentadienyl complex; Ruthenium; Chemistry; Acetonitrile; Yield (engineering); Crystal structure; Medicinal chemistry; Nuclear magnetic resonance spectroscopy; Crystallography; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"category_scores_codex":[0.02277622,0.04791297,0.04822526,0.02513672,0.0209174,0.01656459,0.03095283,0.0271276,0.001435054],"category_scores_gemma":[0.01050674,0.05444477,0.02442664,0.04521581,0.02799266,0.02404367,0.02219532,0.03575503,0.009409385],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.01910386,"about_ca_system_score_gemma":0.01651189,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009584944,"about_ca_topic_score_gemma":0.01273594,"domain_scores_codex":[0.8340295,0.013796,0.03933322,0.04210243,0.03032981,0.04040905],"domain_scores_gemma":[0.8756161,0.01531188,0.03207876,0.03486305,0.01426585,0.02786434],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.01523691,0.01983633,0.004865578,0.01239663,0.02291106,0.007432528,0.008012388,0.003908742,0.7622592,0.000840593,0.01351804,0.1287819],"study_design_scores_gemma":[0.03934527,0.007605501,0.01570291,0.009496452,0.02563526,0.00928982,0.007370064,0.005305728,0.8232053,0.003534316,0.007253837,0.04625554],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8830157,0.01826398,0.002945075,0.003169641,0.009926347,0.02841536,0.04066404,0.012002,0.001597853],"genre_scores_gemma":[0.8534782,0.06754447,0.001680458,0.005025404,0.01357788,0.008969462,0.03182084,0.01778816,0.0001151645],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08252642,"threshold_uncertainty_score":0.9994777,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008557957750394743,"score_gpt":0.2033862601682346,"score_spread":0.1948283024178399,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}