{"id":"W2334943391","doi":"10.1021/ma401263q","title":"Structure–Activity Relationships for Anion-Responsive Poly(squaramides): Support for an Analyte-Induced Noncovalent Polymer Cross-Linking Mechanism","year":2013,"lang":"en","type":"article","venue":"Macromolecules","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Alfred P. Sloan Foundation","keywords":"Squaramide; Chemistry; Polymer; Hydrogen bond; Non-covalent interactions; Combinatorial chemistry; Fluorescence; Polymer chemistry; Organic chemistry; Molecule; Organocatalysis; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.000264848,0.000375106,0.0003471986,0.0001647617,0.0006403885,0.0003096514,0.000267177,0.0004044026,0.0005765827],"category_scores_gemma":[0.0002283515,0.0003808193,0.0003132423,0.0001629281,0.00005657141,0.0003442481,0.00005905194,0.0003232199,0.0000239349],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001345805,"about_ca_system_score_gemma":0.00009831685,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002486736,"about_ca_topic_score_gemma":0.00008281034,"domain_scores_codex":[0.9978558,0.00009512623,0.000444311,0.0007246551,0.0003204795,0.0005596417],"domain_scores_gemma":[0.9982851,0.0002089999,0.0003154645,0.0006106157,0.0003564413,0.0002234453],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002443804,0.00008058122,0.0002177498,0.00009819913,0.00008287165,0.000005261503,0.0001817854,0.00004100195,0.9903529,0.001870777,0.00006573496,0.0067588],"study_design_scores_gemma":[0.001094048,0.0003069381,0.0009100782,0.00002745057,0.00008030474,0.00004207032,0.0001790666,0.01465638,0.975624,0.006252414,0.0003585349,0.0004686628],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9591531,0.00006134627,0.0389134,0.0001284891,0.000274771,0.0006851814,0.0002930756,0.0001598884,0.0003307895],"genre_scores_gemma":[0.9949501,0.000003015234,0.003072557,0.0001292521,0.0002720837,0.0002639494,0.0002842246,0.0001024038,0.000922478],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03584084,"threshold_uncertainty_score":0.9998644,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03391102501053152,"score_gpt":0.2964068306916273,"score_spread":0.2624958056810958,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}