{"id":"W2335382679","doi":"10.1021/ja2062715","title":"Regioselective Activation of Glycosyl Acceptors by a Diarylborinic Acid-Derived Catalyst","year":2011,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":205,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Regioselectivity; Glycosyl; Glycosidic bond; Catalysis; Glycosyl donor; Glycosylation; Carbohydrate chemistry; Carbohydrate; Organic chemistry; Arabinose; Diol; Stereochemistry; Biochemistry; Xylose; Enzyme","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001564528,0.0004274157,0.0001991053,0.0001873964,0.0001066493,0.0002814866,0.0003067972,0.00020766,0.001072334],"category_scores_gemma":[0.0001660789,0.0001348615,0.0001112327,0.0001792386,0.0002016099,0.0002529086,0.000263457,0.0005221479,0.0005665278],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003436448,"about_ca_system_score_gemma":0.0002252202,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003439985,"about_ca_topic_score_gemma":0.0009672573,"domain_scores_codex":[0.9999053,0.00001200176,0.000007264277,0.00002283158,0.00002325207,0.00002934973],"domain_scores_gemma":[0.9999548,0.000007961957,0.00001345125,0.000006210502,0.000005985474,0.00001159994],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009005365,0.00002294847,0.0001245704,0.00004625813,0.000005713176,0.00004479487,0.00002416468,0.0001119882,0.994825,0.0006262215,0.00009521108,0.003983202],"study_design_scores_gemma":[0.000008461896,0.00005365437,0.0001106052,0.000001330279,0.000003331862,0.00006030775,0.000004312164,0.0004021304,0.9984669,0.00003615576,0.0008501041,0.000002625254],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9744748,0.001170525,0.01463034,0.0001256527,0.00006613008,0.00004883471,0.000227879,0.000268053,0.008987698],"genre_scores_gemma":[0.9943204,0.0005505696,0.002685265,0.00002541584,0.000006222448,0.00001026414,0.0001558387,0.00003342584,0.002212674],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001072334,"threshold_uncertainty_score":0.003587365,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01457839363500253,"score_gpt":0.2258307266577874,"score_spread":0.2112523330227849,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}