{"id":"W2335427826","doi":"10.1021/jp210093n","title":"ATR-FTIR Studies on the Adsorption/Desorption Kinetics of Dimethylarsinic Acid on Iron–(Oxyhydr)oxides","year":2012,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Arsenic contamination and mitigation","field":"Environmental Science","cited_by":43,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University","funders":"American Chemical Society Petroleum Research Fund","keywords":"Desorption; Adsorption; Goethite; Chemistry; Chloride; Arsenic; Inorganic chemistry; Hematite; Reaction rate constant; Aqueous solution; Phosphate; Fourier transform infrared spectroscopy; Hydrogen chloride; Kinetics; Chemical engineering; Organic chemistry; Mineralogy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002783283,0.000321675,0.0002132128,0.0003073528,0.00017275,0.000133494,0.000291606,0.000240367,0.0007026443],"category_scores_gemma":[0.0002626499,0.0001360497,0.0002667344,0.0002451148,0.0001599197,0.0002792919,0.0001079413,0.0003625361,0.0002458214],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001568993,"about_ca_system_score_gemma":0.00008583327,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001021984,"about_ca_topic_score_gemma":0.0009810256,"domain_scores_codex":[0.9998704,0.00001692041,0.000009604215,0.0000279308,0.00004794969,0.00002716067],"domain_scores_gemma":[0.9998202,0.00007127539,0.00004299032,0.00001177007,0.0000437992,0.0000100361],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003992979,0.000012383,0.0002847508,0.00003704181,0.000003692491,0.00001901336,0.00002940312,0.0001167328,0.9986653,0.00002287676,0.000009718386,0.0007592189],"study_design_scores_gemma":[0.000002434658,0.0001009814,0.00301205,0.000002877122,0.000006731549,0.0000388791,0.00003377533,0.001747528,0.9947197,0.0000150777,0.0003155324,0.000004210632],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969105,0.0004640153,0.001738619,0.00002029046,0.000004962993,0.000009614381,0.0001596237,0.00002100992,0.0006712992],"genre_scores_gemma":[0.9941869,0.0007795644,0.003486974,0.00001786749,0.000007136488,0.00001452518,0.0002410142,0.00001299979,0.001253109],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001021984,"threshold_uncertainty_score":0.002350569,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02292720414802369,"score_gpt":0.2728403645971208,"score_spread":0.2499131604490971,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}