{"id":"W2335486416","doi":"10.1021/om201104f","title":"Synthesis and Structure of Silver and Rhodium 1,2,3-Triazol-5-ylidene Mesoionic Carbene Complexes","year":2011,"lang":"en","type":"article","venue":"Organometallics","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":90,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Government of Ontario","keywords":"Mesoionic; Rhodium; Chemistry; Carbene; Transmetalation; Cationic polymerization; Bimetallic strip; Denticity; Chemoselectivity; Medicinal chemistry; Stereochemistry; Polymer chemistry; Catalysis; Crystallography; Organic chemistry; Crystal structure","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001389833,0.0002333861,0.0002309637,0.0002025691,0.0001744675,0.0004391605,0.0006969433,0.0003134963,0.001374155],"category_scores_gemma":[0.0002210607,0.0001406498,0.0001101022,0.0001711188,0.0001580701,0.0001778382,0.000294612,0.000343123,0.0006038179],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005718485,"about_ca_system_score_gemma":0.0002309991,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000521147,"about_ca_topic_score_gemma":0.0007248924,"domain_scores_codex":[0.9998766,0.00002000497,0.00001192036,0.00002207912,0.00003552645,0.00003379116],"domain_scores_gemma":[0.9999268,0.000007375103,0.00001659499,0.0000102436,0.00001319846,0.00002575254],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000161954,0.00004290443,0.0001261321,0.00009206118,0.000009468293,0.0001420086,0.00005231634,0.0006693369,0.9930266,0.001568384,0.0001835514,0.003925261],"study_design_scores_gemma":[0.00007269795,0.0003399107,0.0006371637,0.000006539665,0.00001392558,0.000260052,0.00002335011,0.002041774,0.9899999,0.0001160685,0.006468597,0.00002008841],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9792951,0.002493335,0.008346335,0.0002170985,0.00004178731,0.0001278632,0.0003107474,0.0002208545,0.008946826],"genre_scores_gemma":[0.9881578,0.0006023484,0.005340694,0.00004971072,0.00000638108,0.00005664498,0.0002954283,0.00002686827,0.005464111],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001374155,"threshold_uncertainty_score":0.004597008,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01484987299044365,"score_gpt":0.206010216988419,"score_spread":0.1911603439979753,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}