{"id":"W2335535005","doi":"10.1021/ja301180v","title":"An Isolable NHC-Stabilized Silylene Radical Cation: Synthesis and Structural Characterization","year":2012,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":81,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Japan Society for the Promotion of Science; Ministère de l'Économie, de la Science et de l'Innovation - Québec","keywords":"Chemistry; Silylene; Characterization (materials science); Computational chemistry; Stereochemistry; Organic chemistry; Nanotechnology; Silicon","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002645073,0.0001884752,0.0004165726,0.00001649022,0.0001583618,0.00007675901,0.0004175627,0.00008572844,0.0009255306],"category_scores_gemma":[0.000220125,0.0001311158,0.0002693521,0.0002431495,0.0003630341,0.0004187456,0.00009013963,0.0002868824,0.000001913857],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001596778,"about_ca_system_score_gemma":0.00006610394,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007662884,"about_ca_topic_score_gemma":8.945274e-8,"domain_scores_codex":[0.9986413,0.00005529429,0.0004952737,0.0001590149,0.0003690636,0.000280013],"domain_scores_gemma":[0.9982378,0.0001981768,0.0008892869,0.0003062286,0.0001293597,0.0002391529],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004103184,0.0001116307,0.0223647,0.00002344012,0.00009046929,1.543803e-7,0.0004428154,5.019614e-7,0.9720708,0.0000136322,0.0000645555,0.004776226],"study_design_scores_gemma":[0.0003012962,0.0000201082,0.05875356,0.00004164333,0.0001427805,0.0001323369,0.000548318,0.0004572083,0.9361042,0.00002656693,0.003243919,0.0002280011],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982035,0.0000921844,0.0002027843,0.001245674,0.0001233283,0.00003268057,0.0000187708,0.00002236159,0.00005874504],"genre_scores_gemma":[0.9972419,0.0001396922,0.001194274,0.0004394407,0.00088341,0.000003432116,0.00001025062,0.00002984307,0.00005774259],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03638886,"threshold_uncertainty_score":0.9999878,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01036989083110484,"score_gpt":0.2372126960240361,"score_spread":0.2268428051929313,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}