{"id":"W2335553663","doi":"10.1021/om201133r","title":"Factors Influencing the Outcomes of Intermolecular C–H Activations of Hydrocarbons Initiated by CpW(NO)(CH<sub>2</sub>CMe<sub>3</sub>)(η<sup>3</sup>-allyl) Complexes (Cp = η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub> (Cp*), η<sup>5</sup>-C<sub>5</sub>Me<sub>4</sub>H (Cp′))","year":2012,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Methylcyclohexane; Hydrocarbon; Neopentane; Intramolecular force; Migratory insertion; Medicinal chemistry; Ligand (biochemistry); Alkyl; Stereochemistry; Diene; Reductive elimination; Group 2 organometallic chemistry; Photochemistry; Molecule; Organic chemistry; Toluene; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001879682,0.0002088976,0.0001063693,0.00007445016,0.0001463131,0.000412625,0.0002030717,0.0002055955,0.002225622],"category_scores_gemma":[0.0006838448,0.0001546495,0.00008684579,0.00009810894,0.0002819287,0.0003723749,0.0001631716,0.0003853212,0.0003567938],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002526437,"about_ca_system_score_gemma":0.0002157035,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009646455,"about_ca_topic_score_gemma":0.002272899,"domain_scores_codex":[0.9998502,0.00001528672,0.000008864901,0.00002920639,0.00003369099,0.00006282001],"domain_scores_gemma":[0.9997202,0.0001253698,0.00007081191,0.0000141346,0.00003307629,0.00003642391],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003904394,0.00003401631,0.001038743,0.00007177784,0.00001201081,0.00007995051,0.00009722161,0.0005293891,0.9955119,0.0003898553,0.0000925975,0.001752046],"study_design_scores_gemma":[0.000005788775,0.0001153397,0.003263053,0.000003093819,0.000006997942,0.00002243762,0.0000666887,0.001024153,0.995106,0.00004673923,0.0003348312,0.000004913296],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981527,0.0001001542,0.0003156623,0.00001674686,0.000004437285,0.000009121724,0.00007289989,0.00001473073,0.001313534],"genre_scores_gemma":[0.9994377,0.00006159383,0.00008864521,0.000004229163,0.000001088502,0.000005018913,0.00005362987,0.000005970097,0.0003420383],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002225622,"threshold_uncertainty_score":0.007445395,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02212021330777591,"score_gpt":0.2317894960216108,"score_spread":0.2096692827138349,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}