{"id":"W2335553663","doi":"10.1021/om201133r","title":"Factors Influencing the Outcomes of Intermolecular C–H Activations of Hydrocarbons Initiated by CpW(NO)(CH<sub>2</sub>CMe<sub>3</sub>)(η<sup>3</sup>-allyl) Complexes (Cp = η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub> (Cp*), η<sup>5</sup>-C<sub>5</sub>Me<sub>4</sub>H (Cp′))","year":2012,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Methylcyclohexane; Hydrocarbon; Neopentane; Intramolecular force; Migratory insertion; Medicinal chemistry; Ligand (biochemistry); Alkyl; Stereochemistry; Diene; Reductive elimination; Group 2 organometallic chemistry; Photochemistry; Molecule; Organic chemistry; Toluene; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","research_integrity","insufficient_payload"],"category_scores_codex":[0.003791243,0.007569731,0.009312457,0.003848308,0.003068368,0.001506253,0.007699338,0.003777363,0.001319179],"category_scores_gemma":[0.004572315,0.007260074,0.006065296,0.009307699,0.003861523,0.004502597,0.004550599,0.005765488,0.001348413],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00285271,"about_ca_system_score_gemma":0.001988456,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002710793,"about_ca_topic_score_gemma":0.0002758639,"domain_scores_codex":[0.9673293,0.002224435,0.00983109,0.006247829,0.006607725,0.00775964],"domain_scores_gemma":[0.9732854,0.004692617,0.006487948,0.009368809,0.002528987,0.003636262],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004870845,0.004306609,0.01062448,0.001431617,0.008886428,0.0001065036,0.00707953,0.001886318,0.9494575,0.0005113499,0.001701473,0.01352116],"study_design_scores_gemma":[0.004725079,0.0005727195,0.01082031,0.001035863,0.005490134,0.0002427697,0.007044504,0.003610769,0.9563733,0.0007077985,0.002401782,0.006974909],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9826113,0.002740095,0.001276258,0.0007954938,0.0008005227,0.003431951,0.004543686,0.001857007,0.001943716],"genre_scores_gemma":[0.9852679,0.003082358,0.0002633374,0.001128531,0.00145196,0.0009393946,0.005412972,0.00234126,0.0001122221],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006915917,"threshold_uncertainty_score":0.9995937,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02212021330777591,"score_gpt":0.2317894960216108,"score_spread":0.2096692827138349,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}