{"id":"W2335769133","doi":"10.1021/om5003655","title":"Analysis of Stereochemistry Control in Homogeneous Olefin Polymerization Catalysis","year":2014,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"Natural Sciences and Engineering Research Council of Canada; Saudi Basic Industries Corporation","keywords":"Chemistry; Ligand (biochemistry); Monomer; Steric effects; Olefin polymerization; Polymerization; Catalysis; Olefin fiber; Metallocene; Stereochemistry; Chain (unit); Polymer chemistry; Crystallography; Computational chemistry; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002986448,0.0003068568,0.001062946,0.0006837102,0.00005547478,0.00004334128,0.0005105918,0.0001760981,0.0222531],"category_scores_gemma":[0.0002182877,0.0003167136,0.0005120892,0.003029319,0.0001109038,0.00009042573,0.0000901832,0.0001365942,0.00002613199],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008555,"about_ca_system_score_gemma":0.00004503892,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001294353,"about_ca_topic_score_gemma":0.0001769286,"domain_scores_codex":[0.9978221,0.00004944619,0.0008138018,0.0005521286,0.0004031851,0.0003593374],"domain_scores_gemma":[0.998129,0.0002216006,0.0003971339,0.001035615,0.00008658189,0.0001301029],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002737081,0.0004129578,0.04779999,0.0001103946,0.002549889,0.000003915699,0.0001934148,0.0007038728,0.9232717,0.0002553852,0.000002605994,0.02466852],"study_design_scores_gemma":[0.002461118,0.0000566084,0.03733546,0.0000611441,0.01400209,0.00001167927,0.000545819,0.05522623,0.8799067,0.0001738629,0.00859414,0.001625151],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9838555,0.0003516989,0.003660235,0.0000787699,0.000022823,0.00004673786,0.0001299514,0.00005559589,0.01179868],"genre_scores_gemma":[0.997524,0.0000494009,0.0001248269,0.00005957668,0.00005694717,0.00001731236,0.0005081122,0.00004393491,0.001615857],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05452235,"threshold_uncertainty_score":0.9999285,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005113097803874468,"score_gpt":0.1933912994558395,"score_spread":0.188278201651965,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}