{"id":"W2335769133","doi":"10.1021/om5003655","title":"Analysis of Stereochemistry Control in Homogeneous Olefin Polymerization Catalysis","year":2014,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"Natural Sciences and Engineering Research Council of Canada; Saudi Basic Industries Corporation","keywords":"Chemistry; Ligand (biochemistry); Monomer; Steric effects; Olefin polymerization; Polymerization; Catalysis; Olefin fiber; Metallocene; Stereochemistry; Chain (unit); Polymer chemistry; Crystallography; Computational chemistry; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001064684,0.0002800139,0.0003209895,0.0008805689,0.0001847046,0.0004276649,0.000378473,0.0001566954,0.0006391546],"category_scores_gemma":[0.002372081,0.0001627443,0.0004646843,0.000485887,0.0006464266,0.0004171962,0.0002400699,0.0003712456,0.0001078904],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005089901,"about_ca_system_score_gemma":0.0006284482,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001011867,"about_ca_topic_score_gemma":0.0007562588,"domain_scores_codex":[0.9994546,0.0001239688,0.00002171523,0.0001113068,0.0002207392,0.0000677632],"domain_scores_gemma":[0.9982494,0.0009186543,0.0003809797,0.0002078727,0.0001771386,0.00006596791],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008788554,0.0003232518,0.03345384,0.0001992184,0.0002970892,0.0002287955,0.0001531226,0.3070785,0.4885966,0.03952122,0.0008667546,0.1284027],"study_design_scores_gemma":[0.00002084136,0.0002675067,0.01571964,0.000003414665,0.00004317392,0.000042494,0.00002540292,0.8499072,0.1244202,0.008704625,0.0007971455,0.00004820765],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6564194,0.0001250239,0.341114,0.00004162964,0.00001044369,0.0000322633,0.0002566258,0.0004596536,0.001540928],"genre_scores_gemma":[0.9736567,0.00004303328,0.02571852,0.00001338745,0.00001166011,0.00004264687,0.0002170919,0.00004922613,0.0002478577],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001064684,"threshold_uncertainty_score":0.005630672,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005113097803874468,"score_gpt":0.1933912994558395,"score_spread":0.188278201651965,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}