{"id":"W2338047348","doi":"10.1021/acs.chemmater.5b01986","title":"Local Structure of Rare-Earth Fluorides in Bulk and Core/Shell Nanocrystalline Materials","year":2015,"lang":"en","type":"article","venue":"Chemistry of Materials","topic":"Luminescence Properties of Advanced Materials","field":"Materials Science","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria; University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Nanocrystalline material; Materials science; Dopant; Crystallography; Nanocrystal; Powder diffraction; Luminescence; Chemical physics; Doping; Nanotechnology; Chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007263114,0.0003686705,0.001091006,0.00005943678,0.0000306904,0.00007629051,0.000479958,0.0002371299,0.001817357],"category_scores_gemma":[0.0004380975,0.0003150346,0.00003292326,0.0001125701,0.0006974361,0.0003423093,0.0003514757,0.00005544611,0.00001343818],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005200379,"about_ca_system_score_gemma":0.0001482568,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002252787,"about_ca_topic_score_gemma":0.000006283871,"domain_scores_codex":[0.9973034,0.00008260248,0.001246138,0.0005116677,0.0004111915,0.0004449732],"domain_scores_gemma":[0.9983273,0.00005863403,0.0006378998,0.0005341866,0.0002686296,0.0001733124],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007186339,0.00006088075,0.00005625731,0.00142664,0.000008357782,0.00001325947,0.0002594471,0.0001078001,0.9972039,0.00003124474,0.00007653485,0.00003707042],"study_design_scores_gemma":[0.001213109,0.00009264426,0.0001154065,0.0003395921,0.00001912819,0.00005008349,0.0002594996,0.000001168736,0.9963411,0.001086259,0.0001693698,0.0003126439],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976403,0.0003102912,0.00002237402,0.00004586804,0.0006720113,0.00031118,0.0008707048,0.00005081033,0.00007646536],"genre_scores_gemma":[0.9961148,0.00005436483,0.003352245,0.00002197192,0.0001597273,0.00001323394,0.00008200264,0.00004327404,0.0001584106],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003329871,"threshold_uncertainty_score":0.9999302,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01772414504610405,"score_gpt":0.2365054682021325,"score_spread":0.2187813231560284,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}