{"id":"W2338709039","doi":"10.1039/c6ra05865e","title":"Synthesis, structure and conformational mobility of tetra-substituted cyanomethoxy p-tert-butylcalix[4]arenes","year":2016,"lang":"en","type":"article","venue":"RSC Advances","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Bentley (Canada)","funders":"Australian Institute of Nuclear Science and Engineering","keywords":"Tetra; Nitrile; Calixarene; Chemistry; Amide; Stereochemistry; Crystallography; Medicinal chemistry; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00005811047,0.0001545844,0.0002177733,0.00002111927,0.00006249536,0.00001461911,0.0001706113,0.00008856507,0.001374782],"category_scores_gemma":[0.0002784167,0.0001065979,0.00005640066,0.00006409861,0.0002616041,0.0002696704,0.00004706514,0.00006092411,0.000002217081],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001931635,"about_ca_system_score_gemma":0.00003449885,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004222265,"about_ca_topic_score_gemma":0.000002562157,"domain_scores_codex":[0.9991436,0.00001546478,0.0002645182,0.0002282623,0.0001858914,0.0001622542],"domain_scores_gemma":[0.9991127,0.0003690509,0.0001319656,0.0002560791,0.00006458552,0.00006564697],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005583201,0.00003632308,0.01098867,0.0003474593,0.00004098931,0.000002345515,0.00004429823,0.00001009617,0.9573391,0.001090786,0.00001009765,0.03003398],"study_design_scores_gemma":[0.0002641664,0.000005116416,0.001620511,0.0001098074,0.00001892302,0.00002220481,0.00009721625,0.000023172,0.9868636,0.004026689,0.00678711,0.000161532],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.994015,0.001302246,0.001358223,0.00006346522,0.00004242574,0.00003665181,0.0004224108,0.0000473489,0.002712241],"genre_scores_gemma":[0.9981566,0.0001534879,0.00148181,0.00001433961,0.00005664318,0.00001417566,0.00002254248,0.000007961455,0.00009244664],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02987245,"threshold_uncertainty_score":0.9995381,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01077978695908314,"score_gpt":0.2454704830397941,"score_spread":0.234690696080711,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}