{"id":"W2341136313","doi":"10.1002/aic.15165","title":"Ultrasonically enhanced bulk ATRP of methyl methacrylate at high conversion with good livingness and control","year":2016,"lang":"en","type":"article","venue":"AIChE Journal","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada; McMaster University","keywords":"Polymerization; Dispersity; Methyl methacrylate; Radical polymerization; Atom-transfer radical-polymerization; Materials science; Polymer chemistry; Living free-radical polymerization; Bulk polymerization; Polymer; Chain transfer; Chemical engineering; Chemistry; Photochemistry; Composite material","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000125532,0.0002856881,0.0001535475,0.0001516865,0.00007882246,0.0001586594,0.000132811,0.0001562345,0.001151199],"category_scores_gemma":[0.0001677095,0.0001421869,0.0001398013,0.0001388751,0.0001882889,0.0002858549,0.0001949388,0.0005006443,0.00041096],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001468355,"about_ca_system_score_gemma":0.000099957,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002084945,"about_ca_topic_score_gemma":0.0003834473,"domain_scores_codex":[0.9999024,0.0000125916,0.000004597536,0.00002646729,0.00003945876,0.00001441447],"domain_scores_gemma":[0.999863,0.00003751546,0.0000447386,0.00001474888,0.0000273789,0.00001261887],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000009167972,0.000003036278,0.00001777829,0.00001217741,5.495057e-7,0.00001064852,0.000008010232,0.00002757013,0.9991135,0.00002660832,0.00001203061,0.0007588411],"study_design_scores_gemma":[0.000002747242,0.00005124619,0.0002690304,0.000001098512,0.000002135119,0.00003081813,0.000003031492,0.0004695366,0.9987988,0.00001422351,0.0003558983,0.00000133177],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9839841,0.00139119,0.01193206,0.00007055244,0.00002202401,0.00001844336,0.00006834563,0.0002172105,0.002296077],"genre_scores_gemma":[0.9915025,0.0003891125,0.005635613,0.00002380736,0.00001092913,0.00001480702,0.00006438178,0.00004918207,0.002309699],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001151199,"threshold_uncertainty_score":0.003851175,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003491087943621931,"score_gpt":0.1922355594082768,"score_spread":0.1887444714646548,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}