{"id":"W2342959778","doi":"10.1021/acs.organomet.5b00808","title":"d<sup>10</sup> Nickel Difluorocarbenes and Their Cycloaddition Reactions with Tetrafluoroethylene","year":2015,"lang":"en","type":"article","venue":"Organometallics","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":55,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Ontario Ministry of Economic Development and Innovation","keywords":"Tetrafluoroethylene; Difluorocarbene; Chemistry; Nickel; Yield (engineering); Reactivity (psychology); Polymerization; Metal; Cycloaddition; Metathesis; Medicinal chemistry; Polymer chemistry; Photochemistry; Organic chemistry; Copolymer; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004354512,0.0004026801,0.0003748896,0.0001087505,0.0002362511,0.00005257555,0.000293668,0.0003978457,0.003541139],"category_scores_gemma":[0.0002570778,0.0003315116,0.00006782875,0.000476097,0.0003947637,0.0002550632,0.0001543363,0.0007533509,0.0003316868],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001735442,"about_ca_system_score_gemma":0.0002004937,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002760046,"about_ca_topic_score_gemma":0.00001526142,"domain_scores_codex":[0.9982739,0.0001470438,0.0003740512,0.000510472,0.0002095931,0.0004849542],"domain_scores_gemma":[0.9983199,0.0003522257,0.0001530581,0.0004276229,0.0002068975,0.0005403453],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.001495893,0.002783106,0.02074287,0.0005291385,0.002574636,0.0002413061,0.007498723,0.002464836,0.820927,0.003032739,0.08272389,0.05498584],"study_design_scores_gemma":[0.002583413,0.0003057661,0.0006405025,0.00002397093,0.0002679172,0.0004991565,0.001695905,0.001684964,0.3127036,0.0007509505,0.678181,0.000662829],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9823977,0.001185484,0.0001622227,0.001914903,0.0002654592,0.0002976999,0.0001615748,0.0003255599,0.01328943],"genre_scores_gemma":[0.9847811,0.0004638983,0.0007528833,0.0006346441,0.0005720748,0.00005519352,0.0002142084,0.00009556329,0.01243042],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5954571,"threshold_uncertainty_score":0.9999137,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08048885084887035,"score_gpt":0.345698595627029,"score_spread":0.2652097447781586,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}