{"id":"W2344042629","doi":"10.1002/chem.201600574","title":"Intramolecular Alkene Aminocarbonylation Using Concerted Cycloadditions of Amino‐Isocyanates","year":2016,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; University of Ottawa; AstraZeneca Canada","keywords":"Alkene; Hydroamination; Chemistry; Isocyanate; Intramolecular force; Reactivity (psychology); Combinatorial chemistry; Carbonylation; Organic chemistry; Amination; Nucleophile; Catalysis; Polyurethane","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002724955,0.0005364249,0.0002468487,0.0002253701,0.0001794003,0.0002849854,0.0003097095,0.0002842018,0.001316461],"category_scores_gemma":[0.0002318723,0.0002269157,0.0002645366,0.0001945013,0.0002362698,0.000359479,0.0003848024,0.000646952,0.0005709362],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003405806,"about_ca_system_score_gemma":0.0003391036,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000392766,"about_ca_topic_score_gemma":0.001375898,"domain_scores_codex":[0.9997627,0.00002778857,0.00002093415,0.0000718368,0.00004806882,0.00006861766],"domain_scores_gemma":[0.9999039,0.00001483036,0.00002706219,0.0000175136,0.00001797008,0.0000186621],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009901243,0.00005841367,0.0001598365,0.0001675263,0.00001961485,0.0002619664,0.0001056565,0.0006628962,0.9890817,0.002382129,0.0002307636,0.006770413],"study_design_scores_gemma":[0.00001813321,0.0002186769,0.0004921365,0.000008389507,0.0000141869,0.000192916,0.00001579629,0.001143114,0.9922153,0.0001313146,0.005537128,0.00001293297],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9477093,0.003060176,0.02734276,0.000209034,0.0001783714,0.0002206876,0.0002399457,0.0003924487,0.02064737],"genre_scores_gemma":[0.9855299,0.001781336,0.007889443,0.00007119202,0.00002832863,0.0001054867,0.0001572499,0.0000376865,0.004399356],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001316461,"threshold_uncertainty_score":0.004404008,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02034736949414075,"score_gpt":0.2235501936081151,"score_spread":0.2032028241139744,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}