{"id":"W2345135023","doi":"10.1002/chem.201601819","title":"Hantzsch Ester as a Photosensitizer for the Visible‐Light‐Induced Debromination of Vicinal Dibromo Compounds","year":2016,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":66,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"Ministry of Education of the People's Republic of China; Natural Science Foundation of Jiangsu Province; National Natural Science Foundation of China","keywords":"Vicinal; Photosensitizer; Catalysis; Chemistry; Photocatalysis; Visible spectrum; Photochemistry; Substrate (aquarium); Combinatorial chemistry; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00118564,0.0002580138,0.0002655599,0.00004289867,0.0002904705,0.0001162563,0.0004446981,0.00007246798,0.002949236],"category_scores_gemma":[0.0008728061,0.0001625827,0.0002639767,0.0001438585,0.0001205699,0.0001527752,0.0001047899,0.0002682364,0.00004894488],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000138648,"about_ca_system_score_gemma":0.0001618494,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001674464,"about_ca_topic_score_gemma":2.720489e-7,"domain_scores_codex":[0.9981141,0.00009856977,0.0006942921,0.0003168482,0.0004639486,0.0003122364],"domain_scores_gemma":[0.997591,0.0006511493,0.0005702638,0.0004869086,0.0005216231,0.0001790752],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002423375,0.00006778281,0.0001102011,0.0001268412,0.000118109,0.00002976987,0.0001614782,0.000004870364,0.9892365,0.00002885994,0.003872699,0.006000575],"study_design_scores_gemma":[0.002494825,0.00004250191,0.0003656402,0.0003300442,0.0001297349,0.001785793,0.0002218549,0.0003935095,0.9504711,0.0001844357,0.04333096,0.0002495749],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.934198,0.0001193288,0.03696102,0.00182711,0.0003517886,0.0001357114,0.00005389729,0.00006874504,0.0262844],"genre_scores_gemma":[0.9836006,0.00002519465,0.001693297,0.0001350184,0.001175273,0.000008867662,0.00002772525,0.0000847402,0.01324927],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04940261,"threshold_uncertainty_score":0.9979622,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02827694903082125,"score_gpt":0.2787167586023048,"score_spread":0.2504398095714835,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}