{"id":"W2349797504","doi":"10.1107/s1600536806043029","title":"Trimethylphosphine–tris(pentafluorophenyl)borane","year":2006,"lang":"en","type":"article","venue":"Acta Crystallographica Section E Structure Reports Online","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Borane; Phosphine; Trimethylphosphine; Adduct; Chemistry; Trigonal crystal system; Tris; Lewis acids and bases; Frustrated Lewis pair; Crystallography; Aryl; Group (periodic table); Medicinal chemistry; Stereochemistry; Crystal structure; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001453232,0.000656422,0.0006341637,0.0002413897,0.0003152206,0.0001266686,0.0003139701,0.0007622226,0.006916995],"category_scores_gemma":[0.0001268316,0.0006255874,0.0003995946,0.0009877743,0.0002468805,0.0002621154,0.0001108114,0.0009608367,1.190408e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001453313,"about_ca_system_score_gemma":0.0001521891,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006226457,"about_ca_topic_score_gemma":0.0003998621,"domain_scores_codex":[0.9962777,0.00002773739,0.00120583,0.001108207,0.0007185891,0.0006619249],"domain_scores_gemma":[0.9974709,0.00007273966,0.0007487912,0.001179886,0.0002590835,0.0002686114],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00006208383,0.0003102913,0.0163634,0.0001362701,0.000110067,0.0003444652,0.00002068485,0.00002713246,0.9787569,0.000004632722,0.003206131,0.0006579453],"study_design_scores_gemma":[0.001466193,0.00006921437,0.0203624,0.00006381253,0.0002605313,0.003331857,0.0001793019,0.0000382425,0.3760692,0.002191619,0.5947238,0.001243742],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.993648,0.000697531,0.000044517,0.0006531821,0.0008798999,0.0001599908,0.0002595892,0.0008281874,0.002829082],"genre_scores_gemma":[0.9934614,0.000125323,0.0007723338,0.0001555766,0.002327795,0.00001071378,0.001881465,0.0001332885,0.001132129],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.6026877,"threshold_uncertainty_score":0.9996195,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004528610547092977,"score_gpt":0.2187211264625614,"score_spread":0.2141925159154684,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}