{"id":"W2362025019","doi":"10.1039/c6dt01106c","title":"Thiazoyl phosphines. Design, reactivity, and complexation","year":2016,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Synthesis and Reactivity of Sulfur-Containing Compounds","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Nautical Research Society","funders":"","keywords":"Reactivity (psychology); Chemistry; Combinatorial chemistry; Computational chemistry; Medicine","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001400552,0.0002784079,0.0001506056,0.0001712169,0.0001532836,0.0002689848,0.0003241564,0.0002890727,0.001290376],"category_scores_gemma":[0.0002251932,0.0001954198,0.000091873,0.0002284479,0.0002241394,0.0002675575,0.000242291,0.0003541044,0.0005532902],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002756352,"about_ca_system_score_gemma":0.0001525701,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004157383,"about_ca_topic_score_gemma":0.0006381937,"domain_scores_codex":[0.9999105,0.00001787557,0.000008559192,0.00002420199,0.00002481773,0.00001402889],"domain_scores_gemma":[0.9999508,0.00001252631,0.00001493375,0.000006850954,0.00000804856,0.000006806683],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002654225,0.00002657929,0.0002331294,0.0003691995,0.00001365189,0.0001726114,0.0001242932,0.001066952,0.9796893,0.003192218,0.000445082,0.01440157],"study_design_scores_gemma":[0.00005296334,0.0005362771,0.000458224,0.0000107249,0.00001979633,0.0005096739,0.00003155024,0.001800084,0.9780371,0.0002851941,0.01824735,0.00001115236],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9332121,0.01201247,0.03422819,0.0005599266,0.00008942095,0.0002205049,0.0006245983,0.000569352,0.01848343],"genre_scores_gemma":[0.9787453,0.005424939,0.009404165,0.00009070267,0.00002263328,0.00009804266,0.0002832034,0.00005347152,0.005877499],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001290376,"threshold_uncertainty_score":0.004316747,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03263550610146196,"score_gpt":0.2416893187749412,"score_spread":0.2090538126734792,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}