{"id":"W2363756490","doi":"","title":"Laser Flash Photolysis Studies of Quinoxalines in Acetonitrile Solution","year":2003,"lang":"en","type":"article","venue":"","topic":"Synthesis and Biological Evaluation","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"CAE (Canada)","funders":"","keywords":"Flash photolysis; Excited state; Photochemistry; Acetonitrile; Reaction rate constant; Chemistry; Photosensitizer; Quenching (fluorescence); Ultrafast laser spectroscopy; Laser; Triplet state; Fluorescence; Kinetics; Atomic physics; Organic chemistry; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007446215,0.000189585,0.0001770741,0.00008743494,0.000221911,0.000163649,0.0001519751,0.0001874607,0.001671714],"category_scores_gemma":[0.0001142969,0.00008361835,0.0001225241,0.000103365,0.0001300436,0.0001859612,0.00008116802,0.000236791,0.0003222119],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002746691,"about_ca_system_score_gemma":0.000180829,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001522378,"about_ca_topic_score_gemma":0.001322326,"domain_scores_codex":[0.9999435,0.000004882664,0.00000228087,0.00001211062,0.00002039115,0.00001690863],"domain_scores_gemma":[0.9999409,0.00001839494,0.00001357292,0.000003078624,0.00001635306,0.000007731228],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004284634,0.000006326161,0.00008386715,0.0000390706,0.000002048573,0.00007202088,0.00003470395,0.00008107269,0.998674,0.0000828556,0.00002803842,0.0008532543],"study_design_scores_gemma":[0.000003856815,0.0001069907,0.000712002,0.000003250063,0.000003346076,0.00009421403,0.00002982712,0.0003633967,0.9978042,0.00002358921,0.0008519719,0.000003465083],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9921244,0.002585472,0.002140108,0.00006685589,0.0000169591,0.00001497035,0.0001789086,0.00003757263,0.00283486],"genre_scores_gemma":[0.9929387,0.001727492,0.001382812,0.00002785996,0.000008564854,0.00002212309,0.0002314347,0.00001070164,0.003650292],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001671714,"threshold_uncertainty_score":0.005592406,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.09687730640758521,"score_gpt":0.3359760655767569,"score_spread":0.2390987591691716,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}