{"id":"W2367824961","doi":"","title":"MECHANISM OF CELLULOSE RAPID PYROLYSIS II. MECHANISM ANALYSIS","year":2003,"lang":"en","type":"article","venue":"","topic":"Thermochemical Biomass Conversion Processes","field":"Engineering","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"CAE (Canada)","funders":"","keywords":"Levoglucosan; Glycolaldehyde; Homolysis; Chemistry; Heterolysis; Cellulose; Pyrolysis; Organic chemistry; Photochemistry; Reaction mechanism; Decomposition; Radical; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001386274,0.0001682962,0.0003203944,0.0002814955,0.00003156957,0.000009163149,0.0001907174,0.0001221812,0.007281668],"category_scores_gemma":[0.0000366098,0.0001555231,0.0002221739,0.001138641,0.00001978223,0.00007799869,0.0000370235,0.00007372201,0.00005883884],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000296102,"about_ca_system_score_gemma":0.00001103554,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008149856,"about_ca_topic_score_gemma":0.000002571704,"domain_scores_codex":[0.9990782,0.00001993233,0.0002743164,0.0002004593,0.0002098718,0.000217216],"domain_scores_gemma":[0.9994323,0.00004372965,0.00004386016,0.0003168422,0.00006365559,0.0000995849],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000002429169,0.00002991056,0.00000807897,0.00004086151,0.0006096543,0.000001970452,0.00008439588,0.00006450387,0.9191985,0.07941714,0.0001820745,0.000360452],"study_design_scores_gemma":[0.000173486,0.00002132013,0.000002230267,0.000003027509,0.0003932164,8.23864e-7,0.0000882168,0.001728531,0.9887106,0.00832221,0.0003768201,0.0001794637],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8623645,0.0004318465,0.1034162,0.00004538003,0.0002027861,0.0001362902,0.00001309991,0.0006182707,0.03277167],"genre_scores_gemma":[0.9948302,0.00005314432,0.004041283,0.00003625088,0.000006562165,0.000007427222,0.00000705282,0.00002355449,0.0009945492],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1324657,"threshold_uncertainty_score":0.9936258,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006735555838483857,"score_gpt":0.1842684156431405,"score_spread":0.1775328598046567,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}