{"id":"W2394664881","doi":"10.1021/jo020562w","title":"Synthesis and Characterization of β-Trifluoromethyl-<i>m</i><i>eso</i>-tetraphenylporphyrins","year":2003,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":54,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Trifluoromethyl; Chemistry; Tetraphenylporphyrin; Steric effects; Trifluoromethylation; Cyclic voltammetry; Medicinal chemistry; Porphyrin; Stereochemistry; Photochemistry; Organic chemistry; Electrochemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0009449273,0.0001463148,0.000295379,0.00002075693,0.00006680259,0.00002244017,0.0003354681,0.00008619965,0.002865747],"category_scores_gemma":[0.0003714222,0.0001036999,0.0000690456,0.000190341,0.0001548124,0.0001149908,0.00004139255,0.0001887708,0.000004804014],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002808252,"about_ca_system_score_gemma":0.0001232726,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001502242,"about_ca_topic_score_gemma":1.151568e-7,"domain_scores_codex":[0.9988615,0.00007334837,0.0004998141,0.0001073678,0.000285726,0.0001722618],"domain_scores_gemma":[0.9986205,0.0002097014,0.0006474042,0.0002714616,0.0001433803,0.0001075796],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003519465,0.0000586778,0.0004804892,0.0001057823,0.00002071478,0.000005698176,0.0001470524,4.380011e-7,0.9989899,0.000006621455,0.00005523965,0.000094189],"study_design_scores_gemma":[0.0002849555,0.00002096596,0.00114955,0.00006665461,0.0000813283,0.0009336533,0.0001395003,8.235409e-7,0.9966698,0.00009907625,0.0004487977,0.0001049467],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976795,0.0004568611,0.0001869803,0.00008678023,0.0001019092,0.00003363306,0.0000152376,0.000009475953,0.001429676],"genre_scores_gemma":[0.9990268,0.0003260467,0.0002981604,0.00002764511,0.00009600702,7.263665e-7,0.000001100254,0.00001784919,0.000205637],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002860943,"threshold_uncertainty_score":0.9980457,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008560139791657888,"score_gpt":0.2042470352068759,"score_spread":0.195686895415218,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}