{"id":"W2396535213","doi":"10.1021/acs.joc.6b00408","title":"Synthesis of Esters by in Situ Formation and Trapping of Diazoalkanes","year":2016,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"University of California, Davis; American Chemical Society Petroleum Research Fund","keywords":"Chemistry; Diazo; Hydrazone; In situ; Carboxylic acid; Trapping; Aryl; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003340674,0.0008621768,0.0005152512,0.000357053,0.0002808483,0.0002684096,0.0005958444,0.0004054878,0.003022231],"category_scores_gemma":[0.0002851608,0.0003562378,0.000472317,0.0002590303,0.000211442,0.0007044026,0.0006760735,0.001063153,0.001920726],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002116197,"about_ca_system_score_gemma":0.0003823572,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002222491,"about_ca_topic_score_gemma":0.0005106786,"domain_scores_codex":[0.9998286,0.00002442579,0.00001975896,0.00003453403,0.00004846728,0.00004412945],"domain_scores_gemma":[0.9998785,0.00001821487,0.00002864115,0.00002204176,0.00002703099,0.00002550994],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006189477,0.00003569335,0.00004819009,0.0003457455,0.0000198496,0.0003182136,0.00006869295,0.0003300319,0.9892861,0.001499827,0.0002602,0.007725654],"study_design_scores_gemma":[0.00001566532,0.0001471739,0.00007912103,0.00001186744,0.00001190227,0.0002002317,0.00001240956,0.0002387265,0.9895312,0.0001602339,0.009580214,0.00001117486],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6352561,0.01353061,0.3063127,0.0006993942,0.001217497,0.001088913,0.002212305,0.001165119,0.03851748],"genre_scores_gemma":[0.8187767,0.01938184,0.1220793,0.0002652644,0.0001714311,0.0007632022,0.001328615,0.0003451504,0.03688856],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003022231,"threshold_uncertainty_score":0.01011032,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006070264364400166,"score_gpt":0.1935206881856741,"score_spread":0.187450423821274,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}