{"id":"W2397269335","doi":"10.1021/acs.joc.5b00064","title":"Synthesis of Unusual <i>N</i>-Acylated Aminosugar Fragments of <i>Mycobacterium marinum</i> Lipooligosaccharide IV","year":2015,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Alberta Glycomics Centre; University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Alberta Glycomics Centre; University of Alberta; Alberta Innovates - Technology Futures","keywords":"Chemistry; Aminosugar; Stereochemistry; Stereoselectivity; Mycobacterium marinum; Total synthesis; Lactam; Diol; Glycosylation; Convergent synthesis; Combinatorial chemistry; Glucosamine; Mycobacterium; Biochemistry; Organic chemistry; Bacteria; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000810319,0.000455358,0.0002513552,0.0001725725,0.0001221563,0.0002390499,0.000301553,0.0001946559,0.0007325627],"category_scores_gemma":[0.0001271442,0.0001387206,0.0002954508,0.0002008645,0.0001397059,0.0002450076,0.0003248577,0.0004439022,0.0005358572],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002676058,"about_ca_system_score_gemma":0.0003072696,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003701295,"about_ca_topic_score_gemma":0.0007474454,"domain_scores_codex":[0.9999309,0.000009463023,0.000005979335,0.00001315848,0.00001513643,0.00002541044],"domain_scores_gemma":[0.9999382,0.000003939778,0.00001933723,0.000007359168,0.00001127747,0.00001979323],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006624631,0.00001780903,0.0001507091,0.00007765643,0.00001141784,0.0002772238,0.00004208427,0.000342927,0.9938048,0.0005536747,0.00004652412,0.00460903],"study_design_scores_gemma":[0.0000134654,0.0002708349,0.0006790462,0.000008944845,0.00001938358,0.0003250195,0.00002953682,0.0005037583,0.992595,0.0001728264,0.005371992,0.00001011095],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9536121,0.002122311,0.03453502,0.0001429563,0.00008512328,0.000172354,0.0006171726,0.0001783741,0.008534617],"genre_scores_gemma":[0.9731083,0.001396941,0.02201462,0.00006297351,0.00001471931,0.00006329056,0.0006275328,0.00004441689,0.002667116],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007325627,"threshold_uncertainty_score":0.002450705,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01391540124701108,"score_gpt":0.2133439707827638,"score_spread":0.1994285695357528,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}