{"id":"W2399812398","doi":"10.1021/acs.analchem.5b02372","title":"Detection, Identification, and Occurrence of Thiotetronic Acids in Drinking Water from Underground Sources by Electrospray Ionization-High Field Asymmetric Waveform Ion Mobility Spectrometry-Quadrupole Time-of-Flight-Mass Spectrometry","year":2015,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Advanced Chemical Sensor Technologies","field":"Engineering","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Ion-mobility spectrometry; Mass spectrometry; Quadrupole time of flight; Quadrupole; Electrospray ionization; Electrospray; Analytical Chemistry (journal); Ion; Ionization; Waveform; Desorption electrospray ionization; Chromatography; Chemical ionization; Atomic physics; Aerospace engineering","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001263726,0.0003090264,0.0000956535,0.0004992449,0.0001477911,0.0001981608,0.0001763835,0.0002646872,0.000512961],"category_scores_gemma":[0.0002659099,0.0000870388,0.0001213321,0.0003765368,0.0001980531,0.0002033897,0.0001798719,0.0001556457,0.0001408822],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000175625,"about_ca_system_score_gemma":0.0002651812,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001108903,"about_ca_topic_score_gemma":0.001870763,"domain_scores_codex":[0.9998727,0.00001410316,0.000009785803,0.00003434244,0.00005548213,0.00001368049],"domain_scores_gemma":[0.9998668,0.00002664878,0.00005242962,0.000006239257,0.00003343651,0.00001431524],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007472469,0.000007321808,0.004006654,0.00003198666,0.000007081971,0.0001013332,0.00004837185,0.00005821641,0.9896924,0.00004320117,0.00002065334,0.005908133],"study_design_scores_gemma":[0.000005129509,0.000262913,0.01426341,0.000009659875,0.00002459653,0.0007150719,0.0001288792,0.001260272,0.9817469,0.00009289567,0.001478805,0.00001140735],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9874949,0.0008394385,0.01011149,0.00004766058,0.00001107273,0.0000249769,0.0003542783,0.00006683552,0.001049323],"genre_scores_gemma":[0.9846761,0.0007255066,0.01338551,0.00003635876,0.000006873965,0.00001633307,0.0003461086,0.00001087658,0.0007962654],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001108903,"threshold_uncertainty_score":0.002204835,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005433457807678318,"score_gpt":0.2103370205798133,"score_spread":0.204903562772135,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}