{"id":"W2404925205","doi":"10.1007/978-3-642-56546-5_190","title":"Time-Resolved Photoelectron Spectroscopy of Excited State Intramolecular Proton Transfer Dynamics","year":2001,"lang":"en","type":"book-chapter","venue":"Springer series in chemical physics","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":false,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"","keywords":"Intramolecular force; Excited state; X-ray photoelectron spectroscopy; Spectroscopy; Atomic physics; Proton; Materials science; Energy transfer; Internal conversion; Time-resolved spectroscopy; Photoemission spectroscopy; Molecular physics; Photochemistry; Chemistry; Nuclear magnetic resonance; Physics; Spectral line","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00008508192,0.001000947,0.001320284,0.00006529321,0.00005998365,0.00003068216,0.0006496391,0.0006475815,0.0006821591],"category_scores_gemma":[0.00001681189,0.001138575,0.0004529153,0.0001477981,0.000722472,0.0001358928,0.0001249932,0.001705854,0.0000174084],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005780124,"about_ca_system_score_gemma":0.0001637152,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002365404,"about_ca_topic_score_gemma":0.00001688332,"domain_scores_codex":[0.9966265,0.000009932065,0.000933102,0.0009520546,0.0005624102,0.0009159805],"domain_scores_gemma":[0.9986649,0.0000593513,0.0001636146,0.0008278462,0.0001384188,0.0001459245],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009837715,0.0002017426,0.0000168499,0.001641433,0.0004057556,0.00005498442,0.0002228108,0.00002280082,0.9933625,0.00209921,0.00005270703,0.0009354202],"study_design_scores_gemma":[0.0008131556,0.0001005922,4.512177e-7,0.0005884824,0.0001304109,0.00001024601,0.00001064582,0.0001851812,0.9625615,0.02811619,0.006521746,0.0009613281],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.2157089,0.001091392,0.001649556,0.00011112,0.00009513659,0.001398875,0.0006132257,0.0004087394,0.778923],"genre_scores_gemma":[0.8171586,0.005844402,0.0009453325,0.0001696625,0.001382236,0.001133333,0.002960165,0.001357767,0.1690485],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6098745,"threshold_uncertainty_score":0.9991064,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006792741098716522,"score_gpt":0.2118786597221458,"score_spread":0.2050859186234293,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}